Fast cascade neutralization of an oxidized sensitizer by an in situ-generated ionic layer of I- species on a nanocrystalline TiO2 electrode
SCIE
SCOPUS
- Title
- Fast cascade neutralization of an oxidized sensitizer by an in situ-generated ionic layer of I- species on a nanocrystalline TiO2 electrode
- Authors
- Jongchul Lim; Taewan Kim; Park, T
- Date Issued
- 2014-09
- Publisher
- Royal Society of Chemistry
- Abstract
- We report a novel way to accelerate the rate of oxidized sensitizer neutralization on nanocrystalline TiO2 electrode surfaces using a novel coadsorbent, 3,4,5-tris-butenyloxy benzoic acid (TD), having three terminal double bonds. H-1 NMR and contact angle measurements revealed that the terminal double bonds reacted with I-2 to form an in situ-generated ionic layer of I- species. Transient absorption spectroscopy (TAS) and electrochemical impedance spectroscopy (EIS) studies demonstrated that I- species neighbouring the cationic dye molecules (D+) accelerate the neutralization (or regeneration) rate (k(D+)), as well as decrease the recombination reactions of photoinduced electrons with D+ (k(1)) and I-3(-) (k(2)). Dye-sensitized solar cells treated with TD exhibit a power conversion efficiency of 10.2%, which is 22% higher due to the simultaneous improvements in J(SC) and V-OC, even at 15% low dye loading levels, compared to the values obtained from a conventional device.
- Keywords
- SOLAR-CELLS; CHARGE RECOMBINATION; LITHIUM IONS; DYE; EFFICIENCY; POLYMER; PERFORMANCE; INTERFACE; KINETICS; STATES
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/10158
- DOI
- 10.1039/C4EE01950D
- ISSN
- 1754-5692
- Article Type
- Article
- Citation
- ENERGY & ENVIRONMENTAL SCIENCE, vol. 7, no. 12, page. 4029 - 4034, 2014-09
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