Facile Synthesis of alpha-Boryl-Substituted Allylboronate Esters Using Stable Bis[(pinacolato)boryl]methylzinc Reagents
SCIE
SCOPUS
- Title
- Facile Synthesis of alpha-Boryl-Substituted Allylboronate Esters Using Stable Bis[(pinacolato)boryl]methylzinc Reagents
- Authors
- Shin, MinKyeong; Kim, Minjae; Hwang, Chiwon; Lee, Hyojae; Kwon, Hyunchul; Park, Jinyoung; Lee, Eunsung; CHO, SEUNG HWAN
- Date Issued
- 2020-03
- Publisher
- AMER CHEMICAL SOC
- Abstract
- Reported herein is the utilization of bis[(pinacolato)boryl]methylzinc halides, whose structures are characterized via single-crystal X-ray analysis, as solid storable reagents for copper-catalyzed coupling with vinyliodonum salts. The reaction proceeds under mild conditions and shows broad scope with respect to vinyliodonium salts, affording various alpha-boryl-substituted allylboronate esters in good yields. Synthetic applications of the obtained products are also demonstrated.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/102501
- DOI
- 10.1021/acs.orglett.0c00721
- ISSN
- 1523-7060
- Article Type
- Article
- Citation
- ORGANIC LETTERS, vol. 22, no. 6, page. 2476 - 2480, 2020-03
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