DC Field | Value | Language |
---|---|---|
dc.contributor.author | Xie, Lilia S. | - |
dc.contributor.author | Park, Sarah S. | - |
dc.contributor.author | Chmielewski, Michal J. | - |
dc.contributor.author | Liu, Hanyu | - |
dc.contributor.author | Kharod, Ruby A. | - |
dc.contributor.author | Yang, Luming | - |
dc.contributor.author | Campbell, Michael G. | - |
dc.contributor.author | Dinca, Mircea | - |
dc.date.accessioned | 2021-06-01T04:51:23Z | - |
dc.date.available | 2021-06-01T04:51:23Z | - |
dc.date.created | 2021-03-08 | - |
dc.date.issued | 2020-10 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/105537 | - |
dc.description.abstract | The extension of reticular chemistry concepts to electrically conductive three-dimensional metal-organic frameworks (MOFs) has been challenging, particularly for cases in which strong interactions between electroactive linkers create the charge transport pathways. Here, we report the successful replacement of tetrathiafulvalene (TTF) with a nickel glyoximate core in a family of isostructural conductive MOFs with Mn2+, Zn2+, and Cd2+. Different coordination environments of the framework metals lead to variations in the linker stacking geometries and optical properties. Single-crystal conductivity data are consistent with charge transport along the linker stacking direction, with conductivity values only slightly lower than those reported for the analogous TTF materials. These results serve as a case study demonstrating how reticular chemistry design principles can be extended to conductive frameworks with significant intermolecular contacts. | - |
dc.language | English | - |
dc.publisher | John Wiley & Sons Ltd. | - |
dc.relation.isPartOf | Angewandte Chemie - International Edition | - |
dc.title | Isoreticular Linker Substitution in Conductive Metal-Organic Frameworks with Through-Space Transport Pathways | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/anie.202004697 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | Angewandte Chemie - International Edition, v.59, no.44, pp.19623 - 19626 | - |
dc.identifier.wosid | 000535051500001 | - |
dc.citation.endPage | 19626 | - |
dc.citation.number | 44 | - |
dc.citation.startPage | 19623 | - |
dc.citation.title | Angewandte Chemie - International Edition | - |
dc.citation.volume | 59 | - |
dc.contributor.affiliatedAuthor | Park, Sarah S. | - |
dc.identifier.scopusid | 2-s2.0-85085475016 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | ELECTRICAL-CONDUCTIVITY | - |
dc.subject.keywordPlus | ABSORPTION-SPECTRA | - |
dc.subject.keywordPlus | TETRATHIAFULVALENE | - |
dc.subject.keywordPlus | NICKEL | - |
dc.subject.keywordPlus | DIMETHYLGLYOXIME | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | TOPOLOGY | - |
dc.subject.keywordPlus | MOF | - |
dc.subject.keywordAuthor | conducting materials | - |
dc.subject.keywordAuthor | glyoximes | - |
dc.subject.keywordAuthor | metal-organic frameworks | - |
dc.subject.keywordAuthor | reticular chemistry | - |
dc.subject.keywordAuthor | stacking interactions | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
library@postech.ac.kr Tel: 054-279-2548
Copyrights © by 2017 Pohang University of Science ad Technology All right reserved.