DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, H. | - |
dc.contributor.author | Kim, M. | - |
dc.contributor.author | Song, H. | - |
dc.contributor.author | Lee, E. | - |
dc.date.accessioned | 2021-06-11T22:50:29Z | - |
dc.date.available | 2021-06-11T22:50:29Z | - |
dc.date.created | 2021-02-03 | - |
dc.date.issued | 2021-02-19 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/106645 | - |
dc.description.abstract | The synthesis of ambiphilic N-heterocyclic carbene ligand, indol-2-ylidene (IdY, A), is described. A series of indolenium precursors (2 a?f) were prepared on a gram scale in good yields. Trapping experiments with elemental selenium, [RhCl(cod)]2 and CuCl provided the expected carbene adducts. Further computational and spectroscopic studies supported the ambiphilicity of IdY, which lies between cyclic (alkyl)(amino)carbenes (CAAC-5) and cyclic (amino)(aryl)carbene (CAArC). The copper complexes (6) show high percent buried volume (% Vbur = 58.1) and allow for carboboration of terminal alkynes within 30 minutes in a demonstration of synthetic utility with good yields and high regioselectivity. ? 2020 Wiley-VCH GmbH | - |
dc.language | English | - |
dc.publisher | Wiley-VCH Verlag | - |
dc.relation.isPartOf | Chemistry - A European Journal | - |
dc.title | Indol-2-ylidene (IdY): Ambiphilic N-Heterocyclic Carbene Derived from Indole** | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/chem.202004879 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | Chemistry - A European Journal, v.27, no.11, pp.3849 - 3854 | - |
dc.identifier.wosid | 000607649700001 | - |
dc.citation.endPage | 3854 | - |
dc.citation.number | 11 | - |
dc.citation.startPage | 3849 | - |
dc.citation.title | Chemistry - A European Journal | - |
dc.citation.volume | 27 | - |
dc.contributor.affiliatedAuthor | Kim, H. | - |
dc.contributor.affiliatedAuthor | Kim, M. | - |
dc.contributor.affiliatedAuthor | Song, H. | - |
dc.contributor.affiliatedAuthor | Lee, E. | - |
dc.identifier.scopusid | 2-s2.0-85099334725 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | METATHESIS CATALYSTS | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordPlus | HYDROGENATION | - |
dc.subject.keywordPlus | RADICALS | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | VERSATILE | - |
dc.subject.keywordPlus | COPPER | - |
dc.subject.keywordPlus | HYDROAMINATION | - |
dc.subject.keywordPlus | STABILIZATION | - |
dc.subject.keywordAuthor | ambiphilic carbenes | - |
dc.subject.keywordAuthor | copper catalysis | - |
dc.subject.keywordAuthor | indoles | - |
dc.subject.keywordAuthor | ligand design | - |
dc.subject.keywordAuthor | N-heterocyclic carbenes | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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