DC Field | Value | Language |
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dc.contributor.author | Rey Eliseo C. Torrejos | - |
dc.contributor.author | Erwin C. Escobar | - |
dc.contributor.author | HAN, JEONG WOO | - |
dc.contributor.author | Sang Hoon Min | - |
dc.contributor.author | YOOK, HYUN WOO | - |
dc.contributor.author | Khino J. Parohinog | - |
dc.contributor.author | Sangho Koo | - |
dc.contributor.author | Hern Kim | - |
dc.contributor.author | Grace M. Nisola | - |
dc.contributor.author | Wook-Jin Chung | - |
dc.date.accessioned | 2021-11-21T06:50:13Z | - |
dc.date.available | 2021-11-21T06:50:13Z | - |
dc.date.created | 2021-11-19 | - |
dc.date.issued | 2021-11 | - |
dc.identifier.issn | 1385-8947 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/107581 | - |
dc.description.abstract | Multidentate thia-crown ether (CE) diols containing different number of sulfur heteroatoms (2S-4S) were developed as ligands for Pd and Pt. Seven thia-CE diols (denoted as: 2g-2m) were synthesized at 63–93% yields through ring-opening cyclization of bis-epoxide intermediates with 1,2-benzenedithiol. Each thia-CE contains 2 –OH groups as reactive sites for adsorbent fabrication. Initial screening of thia-CE diols through liquid–liquid extraction and density functional theory (DFT) calculations reveal that bidentate (2S, 2O) dithia-CE diol 2i with cavity size Ø2i = 1.61 Å is most selective towards Pd (ØPd2+=1.56 Å) and tetradentate (4S) tetrathia-CE diol 2m (Ø2m = 1.57 Å) to Pt (ØPt2+=1.48 Å). DFT calculations indicate that size-match relationship and denticity difference dictated the coordination stability of 2i with Pd and 2m with Pt, which ultimately defined their respective selectivities. Thia-CEs 2i and 2m were subsequently fabricated as macroporous adsorbent resins (2i-X and 2m-X) via crosslinking of their bis-epoxide derivatives with ethylenediamine in porogenic PEG 400 solvent. Metal ion uptakes were Langmuir-type with high capacities (2i-X: QPd = 212 mg g−1; 2m-X: QPt = 345 mg g−1) and kinetic rates follow the pseudo-second order rate model. Metal ion uptakes are mainly due to neutral coordination with the thia-CEs (84–86%) and to some extent, due to anion complexation with ammonium groups (14–16%). Recovery of Pd by 2i-X and Pt by 2m-X can be carried out effectively and repeatedly in highly acidic feed (6 M HCl) without performance deterioration. Sequential adsorption of Pd by 2i-X and Pt by 2m-X are highly selective in the presence of base metal ions (Mg2+, Al3+, Cr3+, Mn2+, Fe3+, Ni2+, and Pb2+) making these resins ideal for the treatment of highly acidic spent auto-catalyst leachate. | - |
dc.language | English | - |
dc.publisher | Elsevier BV | - |
dc.relation.isPartOf | Chemical Engineering Journal | - |
dc.title | Multidentate thia-crown ethers as hyper-crosslinked macroporous adsorbent resins for the efficient Pd/Pt recovery and separation from highly acidic spent automotive catalyst leachate | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/j.cej.2021.130379 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | Chemical Engineering Journal, v.424 | - |
dc.identifier.wosid | 000707037200056 | - |
dc.citation.title | Chemical Engineering Journal | - |
dc.citation.volume | 424 | - |
dc.contributor.affiliatedAuthor | HAN, JEONG WOO | - |
dc.contributor.affiliatedAuthor | YOOK, HYUN WOO | - |
dc.identifier.scopusid | 2-s2.0-85107891315 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | PLATINUM-GROUP METALS | - |
dc.subject.keywordPlus | AUTOMOBILE CATALYST | - |
dc.subject.keywordPlus | SOLVENT-EXTRACTION | - |
dc.subject.keywordPlus | SELECTIVE ADSORPTION | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURES | - |
dc.subject.keywordPlus | AQUEOUS-SOLUTION | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | PALLADIUM(II) | - |
dc.subject.keywordPlus | PD(II) | - |
dc.subject.keywordPlus | PT(IV) | - |
dc.subject.keywordAuthor | Adsorption | - |
dc.subject.keywordAuthor | Epoxy crosslinking | - |
dc.subject.keywordAuthor | Pd | - |
dc.subject.keywordAuthor | Pt | - |
dc.subject.keywordAuthor | Resins | - |
dc.subject.keywordAuthor | Thiacrown ether | - |
dc.relation.journalWebOfScienceCategory | Engineering, Environmental | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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