DC Field | Value | Language |
---|---|---|
dc.contributor.author | Han, DH | - |
dc.contributor.author | Kim, BS | - |
dc.contributor.author | Choi, SJ | - |
dc.contributor.author | Jung, YJ | - |
dc.contributor.author | Kwak, J | - |
dc.contributor.author | Park, SM | - |
dc.date.accessioned | 2015-06-25T02:31:44Z | - |
dc.date.available | 2015-06-25T02:31:44Z | - |
dc.date.created | 2009-03-13 | - |
dc.date.issued | 2004-01 | - |
dc.identifier.issn | 0013-4651 | - |
dc.identifier.other | 2015-OAK-0000004502 | en_US |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/11136 | - |
dc.description.abstract | Real-time in situ spectroelectrochemical studies have been carried out in N,N'-dimethyl formamide containing lithium trifluoromethane sulfonate as an electrolyte and the results are reported. The results indicate that the primary reduction product of the cyclic form of sulfur, S-8c(2-), undergoes an equilibrium reaction to its linear chain counterpart, S-81(2-), which then dissociates into various products. These two dianions and S-3(-.) were produced along with a minor product, S-4(2-), at the potential corresponding to the first electron transfer. These products were further reduced or dissociated to species including S-7(2-), S-6(2)-, S-5(2-), S-4(2-), S-3(2-), S-2(2-), and S2- at the second electron-transfer step as evidenced by the spectral shifts observed during electrolysis. The reduction reactions are generally chemically reversible, making it possible to use sulfur reduction as a cathode reaction for Li/S batteries. (C) 2004 The Electrochemical Society. | - |
dc.description.statementofresponsibility | open | en_US |
dc.language | English | - |
dc.publisher | ELECTROCHEMICAL SOC INC | - |
dc.relation.isPartOf | JOURNAL OF THE ELECTROCHEMICAL SOCIETY | - |
dc.rights | BY_NC_ND | en_US |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/2.0/kr | en_US |
dc.title | Time-resolved in situ spectroelectrochemical study on reduction of sulfur in N,N '-dimethylformamide | - |
dc.type | Article | - |
dc.contributor.college | 화학과 | en_US |
dc.identifier.doi | 10.1149/1.1773733 | - |
dc.author.google | Han, DH | en_US |
dc.author.google | Kim, BS | en_US |
dc.author.google | Park, SM | en_US |
dc.author.google | Kwak, J | en_US |
dc.author.google | Jung, YJ | en_US |
dc.author.google | Choi, SJ | en_US |
dc.relation.volume | 151 | en_US |
dc.relation.issue | 9 | en_US |
dc.contributor.id | 10200281 | en_US |
dc.relation.journal | JOURNAL OF THE ELECTROCHEMICAL SOCIETY | en_US |
dc.relation.index | SCI급, SCOPUS 등재논문 | en_US |
dc.relation.sci | SCI | en_US |
dc.collections.name | Journal Papers | en_US |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE ELECTROCHEMICAL SOCIETY, v.151, no.9, pp.E283 - E290 | - |
dc.identifier.wosid | 000223622000055 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | E290 | - |
dc.citation.number | 9 | - |
dc.citation.startPage | E283 | - |
dc.citation.title | JOURNAL OF THE ELECTROCHEMICAL SOCIETY | - |
dc.citation.volume | 151 | - |
dc.contributor.affiliatedAuthor | Park, SM | - |
dc.identifier.scopusid | 2-s2.0-4944227580 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 81 | - |
dc.description.scptc | 83 | * |
dc.date.scptcdate | 2018-10-274 | * |
dc.type.docType | Article | - |
dc.subject.keywordPlus | LIQUID-AMMONIA | - |
dc.subject.keywordPlus | ELECTROCHEMICAL REDUCTION | - |
dc.subject.keywordPlus | APROTIC SOLVENTS | - |
dc.subject.keywordPlus | DIMETHYLFORMAMIDE | - |
dc.subject.keywordPlus | POLYSULFIDES | - |
dc.subject.keywordPlus | IDENTIFICATION | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | S-3(-) | - |
dc.subject.keywordPlus | CELLS | - |
dc.subject.keywordPlus | IONS | - |
dc.relation.journalWebOfScienceCategory | Electrochemistry | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Coatings & Films | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Electrochemistry | - |
dc.relation.journalResearchArea | Materials Science | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
library@postech.ac.kr Tel: 054-279-2548
Copyrights © by 2017 Pohang University of Science ad Technology All right reserved.