DC Field | Value | Language |
---|---|---|
dc.contributor.author | Koo, Jin Young | - |
dc.contributor.author | Oh, Jongwon | - |
dc.contributor.author | Hyun, Gyeongeun | - |
dc.contributor.author | Choi, Hee Cheul | - |
dc.contributor.author | Song, Intek | - |
dc.contributor.author | Yoon, Seok Min | - |
dc.date.accessioned | 2022-06-30T05:40:29Z | - |
dc.date.available | 2022-06-30T05:40:29Z | - |
dc.date.created | 2021-10-12 | - |
dc.date.issued | 2021-09 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/113273 | - |
dc.description.abstract | A new oxo-bridged chromium-molybdenum heterometallic complex, O-CrMoHC ([Cr-4(MoO4)(2)O-2(OAc)(4)(DMF)(4)]center dot 2DMF), was synthesized by using a simple solvothermal reaction. In this complex, the octahedrally coordinated Cr(III) and tetrahedrally coordinated Mo(VI) metal centers are bridged by oxo ligands. O-CrMoHC has in-plane pi-conjugation systems, which are interconnected by noncoordinating DMF molecules. The crystals show anisotropic conductivity with respect to the crystal planes, and theoretical calculations were used to study their origins. The O-CrMoHC single crystals exhibited that a relatively high electrical conductivity with an average value of 5.37 x 10(-7) S/cm was observed along the [01-1] direction, but the current level was very low along the [100] direction. This is the first report of anisotropic conductivity observed in the single crystal of a monomeric heterometallic complex. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.relation.isPartOf | INORGANIC CHEMISTRY | - |
dc.title | Anisotropic Electrical Conductivity of a Single-Crystalline Oxo-Bridged (Cr4Mo2VI)-Mo-III Heterometallic Complex | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/acs.inorgchem.1c01618 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | INORGANIC CHEMISTRY, v.60, no.17, pp.13262 - 13268 | - |
dc.identifier.wosid | 000695585400070 | - |
dc.citation.endPage | 13268 | - |
dc.citation.number | 17 | - |
dc.citation.startPage | 13262 | - |
dc.citation.title | INORGANIC CHEMISTRY | - |
dc.citation.volume | 60 | - |
dc.contributor.affiliatedAuthor | Koo, Jin Young | - |
dc.contributor.affiliatedAuthor | Choi, Hee Cheul | - |
dc.identifier.scopusid | 2-s2.0-85114043270 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | TRANSITION-METAL-COMPLEXES | - |
dc.subject.keywordPlus | ACETATE | - |
dc.subject.keywordPlus | CATALYSIS | - |
dc.subject.keywordPlus | CLUSTERS | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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