Synthesis of the Tetrasaccharide Glycone Part of Tetrocarcin A
SCIE
SCOPUS
- Title
- Synthesis of the Tetrasaccharide Glycone Part of Tetrocarcin A
- Authors
- Kang, Jihun; Rhee, Young Ho
- Date Issued
- 2023-02
- Publisher
- American Chemical Society
- Abstract
- A de novo synthesis of the tetrasaccharide fragment of tetrocarcin A is described. The key feature of this approach is highlighted by the regio- and diastereoselective Pd-catalyzed hydroalkoxylation of ene-alkoxyallenes with an unprotected l-digitoxose glycoside. The subsequent reaction with digitoxal in combination with chemoselective hydrogenation generated the target molecule.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/120799
- DOI
- 10.1021/acs.joc.2c02832
- ISSN
- 0022-3263
- Article Type
- Article
- Citation
- Journal of Organic Chemistry, vol. 88, no. 5, page. 3326 - 3329, 2023-02
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- There are no files associated with this item.
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