Bulk-sensitive photoemission spectroscopy of A(2)FeMoO(6) double perovskites (A = Sr, Ba)
SCIE
SCOPUS
- Title
- Bulk-sensitive photoemission spectroscopy of A(2)FeMoO(6) double perovskites (A = Sr, Ba)
- Authors
- Kang, JS; Kim, JH; Sekiyama, A; Kasai, S; Suga, S; Han, SW; Kim, KH; Muro, T; Saitoh, Y; Hwang, C; Olson, CG; Park, BJ; Lee, BW; Shim, JH; Park, JH; Min, BI
- Date Issued
- 2002-09-15
- Publisher
- AMERICAN PHYSICAL SOC
- Abstract
- The electronic structures of Sr2FeMoO6 (SFMO) and Ba2FeMoO6 (BFMO) double perovskites have been investigated using Fe 2p-->3d resonant photoemission spectroscopy (PES) and the Cooper minimum in the Mo 4d photoionization cross section. The states close to the Fermi level are found to have a strongly mixed Mo-Fe t(2g) character, indicating that the Fe valence is far from pure 3+. The Fe 2p(3/2) x-ray absorption spectroscopy spectra reveal the mixed-valent Fe3+-Fe2+ configurations, and a larger Fe2+ component for BFMO than for SFMO, suggesting an operative double exchange interaction. The valence-band PES spectra reveal good agreement with the local-spin-density-approximation (LSDA)+U calculation.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/12088
- DOI
- 10.1103/PHYSREVB.66.113105
- ISSN
- 1098-0121
- Article Type
- Article
- Citation
- PHYSICAL REVIEW B, vol. 66, no. 11, 2002-09-15
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