Temperature-dependent Raman spectroscopy in BaRuO3 systems
SCIE
SCOPUS
- Title
- Temperature-dependent Raman spectroscopy in BaRuO3 systems
- Authors
- Lee, YS; Noh, TW; Park, JH; Lee, KB; Cao, G; Crow, JE; Lee, MK; Eom, CB; Oh, EJ; Yang, IS
- Date Issued
- 2002-06-15
- Publisher
- AMERICAN PHYSICAL SOC
- Abstract
- We investigated the temperature dependence of the Raman spectra of a nine-layer BaRuO3 single crystal and a four-layer BaRuO3 epitaxial film, which show pseudogap formations in their metallic states. From the polarized and depolarized spectra, the observed phonon modes are assigned properly according to the predictions of group theory analysis. In both compounds, with decreasing temperature, while A(1g) modes show a strong hardening, E-g (or E-2g) modes experience a softening or no significant shift. Their different temperature-dependent behaviors could be related to a direct Ru metal bonding through the face sharing of RuO6. It is also observed that another E-2g mode of the oxygen participating in the face sharing becomes split at low temperatures in the four-layer BaRuO3. And, the temperature dependence of the Raman continua between 250 and 600 cm(-1) is strongly correlated to the square of the plasma frequency. Our observations imply that there should be a structural instability in the face-shared structure, which could be closely related to the pseudogap formation of BaRuO3 systems.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/12096
- DOI
- 10.1103/PHYSREVB.65.235113
- ISSN
- 1098-0121
- Article Type
- Article
- Citation
- PHYSICAL REVIEW B, vol. 65, no. 23, 2002-06-15
- Files in This Item:
-
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.