DC Field | Value | Language |
---|---|---|
dc.contributor.author | CHO, SEUNG HWAN | - |
dc.contributor.author | HWANG, CHIWON | - |
dc.contributor.author | JANG, YUNHUI | - |
dc.contributor.author | JUNG, YONGSUK | - |
dc.contributor.author | SEO, JAE YOON | - |
dc.contributor.author | Shin, Kwangmin | - |
dc.date.accessioned | 2024-09-20T01:40:11Z | - |
dc.date.available | 2024-09-20T01:40:11Z | - |
dc.date.created | 2024-08-31 | - |
dc.date.issued | 2024-08 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/124224 | - |
dc.description.abstract | The development of effective strategies to forge C-O and C-S bonds in diverse chemical spaces is of considerable interest in synthetic organic chemistry. Herein we report a versatile approach for the modular synthesis of structurally diverse (thio)ethers and (thio)esters via homologative coupling of α-halodiborylmethane followed by transformation of the introduced diborylmethyl group. This method accommodates a wide array of oxygen- and sulfur-containing molecules, including biologically active compounds. The initial coupling exhibits a broad substrate scope, while subsequent diversification of the diborylmethyl moiety enables access to various structural motifs through deborylative alkylation, Zweifel olefination, and boron-Wittig reaction. This protocol efficiently generates diversely functionalized (thio)ethers and (thio)esters, expanding the toolkit for accessing biologically relevant scaffolds. © 2024 American Chemical Society. | - |
dc.language | English | - |
dc.publisher | American Chemical Society | - |
dc.relation.isPartOf | Organic Letters | - |
dc.title | Diverse Synthesis of (Thio)ethers and (Thio)esters Using Halodiborylmethane as a Transformable C1 Building Block | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/acs.orglett.4c02510 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | Organic Letters, v.26, no.33, pp.7010 - 7014 | - |
dc.identifier.wosid | 001287535700001 | - |
dc.citation.endPage | 7014 | - |
dc.citation.number | 33 | - |
dc.citation.startPage | 7010 | - |
dc.citation.title | Organic Letters | - |
dc.citation.volume | 26 | - |
dc.contributor.affiliatedAuthor | CHO, SEUNG HWAN | - |
dc.contributor.affiliatedAuthor | HWANG, CHIWON | - |
dc.contributor.affiliatedAuthor | JANG, YUNHUI | - |
dc.contributor.affiliatedAuthor | JUNG, YONGSUK | - |
dc.contributor.affiliatedAuthor | SEO, JAE YOON | - |
dc.identifier.scopusid | 2-s2.0-85200848980 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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