Quantum dot–layered double hydroxide composites for near-infrared emitting codes

Abstract

Near-infrared (NIR)-emitting PbS-based quantum dots (QDs) and exfoliated layered double hydroxide (LDH) nanosheets were self-assembled to form photostable composites for NIR-emitting codes. PbS QDs prepared by a pyrolysis synthetic method or PbS-CdS (core-shell) QDs prepared by a cation exchange using PbS QDs were transferred to aqueous solutions by surface ligand exchange to dihydrolipoic acid (DHLA). The DHLA-decorated QDs and exfoliated LDH nanosheets were assembled by electrostatic interactions during vortexing. The QD-LDH composite films prepared by drop-casting exhibit more than 500% higher NIR PL intensities than the counterpart QD films (without LDH matrices) under identical conditions (i.e., QD concentration). Photostability tests under continuous light irradiation reveal that the PbS-CdS QD films are more photostable than the PbS QD films. Formation of the QD-LDH composites gives rise to further enhancement in the photostability of the film. The photostable PbS-CdS QD-LDH composite films were used to create novel NIR-emitting codes. NIR fluorescence images of a pattern of two kinds of PbS-CdS QD-LDH composite films were recorded with an InGaAs CCD camera equipped with optical filters.