Influence of Gas Atmosphere Dew Point on the Galvannealing of CMnSi TRIP Steel

Abstract

The Fe-Zn reaction occurring during the galvannealing of a Si-bearing transformation-induced plasticity (TRIP) steel was investigated by field-emission electron probe microanalysis and field-emission transmission electron microscopy. The galvannealing was simulated after hot dipping in a Zn bath containing 0.13 mass pct Al at 733 K (460 A degrees C). The galvannealing temperature was in the range of 813 K to 843 K (540 A degrees C to 570 A degrees C). The kinetics and mechanism of the galvannealing reaction were strongly influenced by the gas atmosphere dew point (DP). After the galvannealing of a panel annealed in a N-2+10 pct H-2 gas atmosphere with low DPs [213 K and 243 K (-60 A degrees C and -30 A degrees C)], the coating layer consisted of delta (FeZn10) and eta (Zn) phase crystals. The Mn-Si compound oxides formed during intercritical annealing were present mostly at the steel/coating interface after the galvannealing. Galvannealing of a panel annealed in higher DP [263 K and 273 K, and 278 K (-10 A degrees C, 0 A degrees C, and +5 A degrees C)] gas atmospheres resulted in a coating layer consisting of delta and D" (Fe3Zn10) phase crystals, and a thin layer of D" (1) (Fe11Zn40) phase crystals at the steel/coating interface. The Mn-Si oxides were distributed homogeneously throughout the galvannealed (GA) coating layer. When the surface oxide layer thickness on panels annealed in a high DP gas atmosphere was reduced, the Fe content at the GA coating surface increased. Annealing in a higher DP gas atmosphere improved the coating quality of the GA panels because a thinner layer of oxides was formed. A high DP atmosphere can therefore significantly contribute to the suppression of Zn-alloy coating defects on CMnSi TRIP steel processed in hot dip galvanizing lines.