Pd-Catalyzed Asymmetric Intermolecular Hydroalkoxylation of Allene: An Entry to Cyclic Acetals with Activating Group-Free and Flexible Anomeric Control
SCIE
SCOPUS
- Title
- Pd-Catalyzed Asymmetric Intermolecular Hydroalkoxylation of Allene: An Entry to Cyclic Acetals with Activating Group-Free and Flexible Anomeric Control
- Authors
- Lim, W; Kim, J; Rhee, YH
- Date Issued
- 2014-10-01
- Publisher
- AMER CHEMICAL SOC
- Abstract
- A ligand-directed metal-catalyzed asymmetric intermolecular hydroalkoxylation of alkoxyallene is reported. Combined with ring-closing-metathesis, this reaction offers a new atom-efficient synthetic method toward various cyclic acetals with elaborate anomeric control. Synthetic utility of the reaction was demonstrated by the atom-efficient and stereodivergent access to various mono- and disaccharides.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/13898
- DOI
- 10.1021/JA508587F
- ISSN
- 0002-7863
- Article Type
- Article
- Citation
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 136, no. 39, page. 13618 - 13621, 2014-10-01
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