DC Field | Value | Language |
---|---|---|
dc.contributor.author | Goutam Kumar Kole | - |
dc.contributor.author | Tatsuhiro Kojima | - |
dc.contributor.author | Kawano, M | - |
dc.contributor.author | Jagadese J. Vittal | - |
dc.date.accessioned | 2016-03-31T07:59:28Z | - |
dc.date.available | 2016-03-31T07:59:28Z | - |
dc.date.created | 2015-03-06 | - |
dc.date.issued | 2014-02-17 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.other | 2014-OAK-0000030544 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/14317 | - |
dc.description.abstract | A [2+2] cycloaddition reaction has been observed in a number of solids. The cyclobutane ring in a photodimerized material can be cleaved into olefins by UV light and heat. The high thermal stability of the metal-organic salt K2SDC (H2SDC=4,4'-stilbenedicarboxylic acid) has been successfully utilized to investigate the reversible cleavage of a cyclobutane ring. The two polymorphs of K2SDC undergo reversible cyclobutane formation by UV light and cleavage by heat in cycles. Of these, one polymorph retains its single-crystal nature during the reversible processes. Polymorphs are known to show different physical properties and chemical reactivities. This work reveals that the retention of single-crystal nature is strongly associated with the packing of molecules, which is controlled by kinetics and thermodynamics. The photoemissive nature of the products makes this as a promising material for photoswitches and optical data storage devices. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.relation.isPartOf | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.subject | C-C bond cleavage | - |
dc.subject | coordination polymers | - |
dc.subject | cycloaddition | - |
dc.subject | polymorphism | - |
dc.subject | solid-state reactions | - |
dc.subject | 2+2 CYCLOADDITION REACTION | - |
dc.subject | SOLID-STATE | - |
dc.subject | COORDINATION NETWORK | - |
dc.subject | SWITCHES | - |
dc.subject | PHOTODIMERIZATION | - |
dc.subject | TRANSFORMATION | - |
dc.subject | DIARYLETHENES | - |
dc.subject | PHOTOCHROMISM | - |
dc.subject | MEMORIES | - |
dc.title | Reversible Single-Crystal-to-Single-Crystal Photochemical Formation and Thermal Cleavage of a Cyclobutane Ring | - |
dc.type | Article | - |
dc.contributor.college | 첨단재료과학부 | - |
dc.identifier.doi | 10.1002/ANIE.201306746 | - |
dc.author.google | Kole, GK | - |
dc.author.google | Kojima, T | - |
dc.author.google | Kawano, M | - |
dc.author.google | Vittal, JJ | - |
dc.relation.volume | 53 | - |
dc.relation.issue | 8 | - |
dc.relation.startpage | 2143 | - |
dc.relation.lastpage | 2146 | - |
dc.contributor.id | 10648581 | - |
dc.relation.journal | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.53, no.8, pp.2143 - 2146 | - |
dc.identifier.wosid | 000330908600018 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 2146 | - |
dc.citation.number | 8 | - |
dc.citation.startPage | 2143 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 53 | - |
dc.contributor.affiliatedAuthor | Kawano, M | - |
dc.identifier.scopusid | 2-s2.0-84893873936 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 43 | - |
dc.description.scptc | 42 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article | - |
dc.subject.keywordPlus | 2+2 CYCLOADDITION REACTION | - |
dc.subject.keywordPlus | SOLID-STATE | - |
dc.subject.keywordPlus | COORDINATION NETWORK | - |
dc.subject.keywordPlus | SWITCHES | - |
dc.subject.keywordPlus | PHOTODIMERIZATION | - |
dc.subject.keywordPlus | TRANSFORMATION | - |
dc.subject.keywordPlus | DIARYLETHENES | - |
dc.subject.keywordPlus | PHOTOCHROMISM | - |
dc.subject.keywordPlus | MEMORIES | - |
dc.subject.keywordAuthor | C-C bond cleavage | - |
dc.subject.keywordAuthor | coordination polymers | - |
dc.subject.keywordAuthor | cycloaddition | - |
dc.subject.keywordAuthor | polymorphism | - |
dc.subject.keywordAuthor | solid-state reactions | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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