DC Field | Value | Language |
---|---|---|
dc.contributor.author | Cho, SH | - |
dc.contributor.author | Hartwig, JF | - |
dc.date.accessioned | 2016-03-31T08:02:41Z | - |
dc.date.available | 2016-03-31T08:02:41Z | - |
dc.date.created | 2014-07-31 | - |
dc.date.issued | 2013-06-05 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.other | 2013-OAK-0000030160 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/14433 | - |
dc.description.abstract | Most functionalizations of C-H bonds by main-group reagents occur at aryl or methyl groups. We describe a highly regioselective borylation of secondary benzylic C-H bonds catalyzed by an iridium precursor and 3,4,7,8-tetramethyl-1,10-phenanthroline as the ligand. The reaction is directed to the benzylic position by a hydrosilyl substituent. This hydrosilyl directing group is readily deprotected or transformed to other functional groups after the borylation reaction, providing access to a diverse set of secondary benzylboronate esters by C-H borylation chemistry. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | American Chemical Society | - |
dc.relation.isPartOf | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.subject | ROOM-TEMPERATURE REACTIONS | - |
dc.subject | AROMATIC BORYLATION | - |
dc.subject | REGIOSPECIFIC FUNCTIONALIZATION | - |
dc.subject | CONTAINING HETEROCYCLES | - |
dc.subject | COUPLING REACTIONS | - |
dc.subject | ALKYL-HALIDES | - |
dc.subject | INERT SOLVENT | - |
dc.subject | ARENES | - |
dc.subject | ESTERS | - |
dc.subject | BIS(PINACOLATO)DIBORON | - |
dc.title | Iridium-catalyzed borylation of secondary benzylic C-H bonds directed by a hydrosilane | - |
dc.type | Article | - |
dc.contributor.college | 화학과 | - |
dc.identifier.doi | 10.1021/JA403462B | - |
dc.author.google | Cho, Seung Hwan | - |
dc.author.google | Hartwig, John F. | - |
dc.relation.volume | 135 | - |
dc.relation.issue | 22 | - |
dc.relation.startpage | 8157 | - |
dc.relation.lastpage | 8160 | - |
dc.contributor.id | 11362690 | - |
dc.relation.journal | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.135, no.22, pp.8157 - 8160 | - |
dc.identifier.wosid | 000320153100018 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 8160 | - |
dc.citation.number | 22 | - |
dc.citation.startPage | 8157 | - |
dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.volume | 135 | - |
dc.contributor.affiliatedAuthor | Cho, SH | - |
dc.identifier.scopusid | 2-s2.0-84878653240 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 58 | - |
dc.description.scptc | 52 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article | - |
dc.subject.keywordPlus | REGIOSPECIFIC FUNCTIONALIZATION | - |
dc.subject.keywordPlus | COUPLING REACTIONS | - |
dc.subject.keywordPlus | ARENES | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | ESTERS | - |
dc.subject.keywordPlus | HYDROBORATION | - |
dc.subject.keywordPlus | REAGENTS | - |
dc.subject.keywordPlus | BIS(PINACOLATO)DIBORON | - |
dc.subject.keywordPlus | HETEROARENES | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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