Intramolecular oxidative diamination and aminohydroxylation of olefins under metal-free conditions
SCIE
SCOPUS
- Title
- Intramolecular oxidative diamination and aminohydroxylation of olefins under metal-free conditions
- Authors
- Kim, HJ; Cho, SH; Chang, S
- Date Issued
- 2012-03-16
- Publisher
- American Chemical Society
- Abstract
- A metal-free procedure that is simple to operate and convenient to handle was developed for the facile intramolecular oxidative diamination of olefins using an iodobenzene diacetate oxidant and a halide additive to furnish bisindolines at room temperature. The present reaction is featured by mild conditions, a broad substrate scope, and excellent functional group tolerance. The same protocol was successfully extended to the aminohydroxylation.
- Keywords
- N BOND FORMATION; ACTIVATED METHYLENE-COMPOUNDS; C-H BONDS; CONJUGATED DIENES; STEREOSELECTIVE-SYNTHESIS; MECHANISTIC PATHWAYS; HYPERVALENT IODINE; DIRECT AMINATION; ALKENES; CYCLIZATION
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/14436
- DOI
- 10.1021/OL300166Q
- ISSN
- 1523-7060
- Article Type
- Article
- Citation
- ORGANIC LETTERS, vol. 14, no. 6, page. 1424 - 1427, 2012-03-16
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- There are no files associated with this item.
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