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Intermolecular oxidative C-N bond formation under metal-free conditions: Control of Chemoselectivity between Aryl sp(2) and Benzylic sp(3) C-H Bond Imidation SCIE SCOPUS
- Title
- Intermolecular oxidative C-N bond formation under metal-free conditions: Control of Chemoselectivity between Aryl sp(2) and Benzylic sp(3) C-H Bond Imidation
- Date Issued
- 2011-10-19
- Publisher
- American Chemical Society
- Abstract
- A new synthetic approach toward intermolecular oxidative C-N bond formation of arenes has been developed under transition-metal-free conditions. Complete control of chemoselectivity between aryl sp(2) and benzylic sp(3) C-H bond imidation was achieved by the choice of nitrogen sources, representatively being phthalimide and dibenzenesulfonimide, respectively.
- Keywords
- ELECTROPHILIC AROMATIC-SUBSTITUTION; HYPERVALENT IODINE COMPOUNDS; CATALYZED DIRECT AMINATION; NITRENIUM IONS; HETEROCYCLIC-COMPOUNDS; AMBIENT-TEMPERATURE; ACYLNITRENIUM IONS; SINGLE-ELECTRON; AMIDATION; ROUTE
- ISSN
- 0002-7863
- Article Type
- Article
- Citation
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 133, no. 41, page. 16382 - 16385, 2011-10-19
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Related Researcher
- 조승환CHO, SEUNG HWAN
- Dept of Chemistry