DC Field | Value | Language |
---|---|---|
dc.contributor.author | Shin-Geol Kang | - |
dc.contributor.author | Yun-Taek Lee | - |
dc.contributor.author | Hyungphil Chun | - |
dc.contributor.author | Kim, K | - |
dc.date.accessioned | 2016-03-31T08:13:59Z | - |
dc.date.available | 2016-03-31T08:13:59Z | - |
dc.date.created | 2014-03-05 | - |
dc.date.issued | 2014-01-01 | - |
dc.identifier.issn | 0020-1693 | - |
dc.identifier.other | 2014-OAK-0000029164 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/14851 | - |
dc.description.abstract | New topologically constrained tetraaza macropolycycles L-9, L-10, and L-11 containing two o-xylylene (-(CH2)C6H4(CH2)-) bridges have been prepared by the reaction of 1,2-bis(bromomethyl) benzene with 3,14-dimethyl-2,6,13,17-tetraazatricyclo[16.4.0.0(7.12)]docosane (L-1), 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (L-2), or 2,5,5,7,9,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradecane (L-3). The macropolycycle L-9 readily reacts with Cu2+ ion to form [CuL9](2+) in wet methanol. However, L-10 and L-11 do not bind the metal ion in similar conditions. The Cu-N distances [2.048(4)-2.070(4)] and the ligand field strength of [CuL9](ClO4)(2) are considerably longer and weaker, respectively, than those of other related macropolycyclic copper(II) complexes containing two N-(CH2)(2)-N or N-(CH2)(3)-N bridges. The copper(II) complex is extremely stable even in low pH and quite inert against ligand substitution with CN ion. (C) 2013 Elsevier B.V. All rights reserved. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.relation.isPartOf | INORGANICA CHIMICA ACTA | - |
dc.subject | Macropolycycles | - |
dc.subject | Structurally constrained macrocycles | - |
dc.subject | Bridged macrocycles | - |
dc.subject | Crystal structure | - |
dc.subject | Copper(II) complex | - |
dc.subject | CLEAVAGE | - |
dc.subject | LIGANDS | - |
dc.title | Synthesis of new structurally constrained tetraaza macropolycyclic compounds containing two rigid bridges: Crystal structure and chemical properties of a copper(II) complex | - |
dc.type | Article | - |
dc.contributor.college | 첨단재료과학부 | - |
dc.identifier.doi | 10.1016/J.ICA.2013.09.018 | - |
dc.author.google | Kang, SG | - |
dc.author.google | Lee, YT | - |
dc.author.google | Chun, H | - |
dc.author.google | Kim, K | - |
dc.relation.volume | 409 | - |
dc.relation.startpage | 315 | - |
dc.relation.lastpage | 319 | - |
dc.contributor.id | 10104366 | - |
dc.relation.journal | INORGANICA CHIMICA ACTA | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | INORGANICA CHIMICA ACTA, v.409, pp.315 - 319 | - |
dc.identifier.wosid | 000327531500018 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 319 | - |
dc.citation.startPage | 315 | - |
dc.citation.title | INORGANICA CHIMICA ACTA | - |
dc.citation.volume | 409 | - |
dc.contributor.affiliatedAuthor | Kim, K | - |
dc.identifier.scopusid | 2-s2.0-84887573681 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 1 | - |
dc.description.scptc | 1 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article | - |
dc.subject.keywordAuthor | Macropolycycles | - |
dc.subject.keywordAuthor | Structurally constrained macrocycles | - |
dc.subject.keywordAuthor | Bridged macrocycles | - |
dc.subject.keywordAuthor | Crystal structure | - |
dc.subject.keywordAuthor | Copper(II) complex | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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