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Cited 16 time in webofscience Cited 15 time in scopus
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dc.contributor.authorLee, E-
dc.contributor.authorY-
dc.contributor.authorulov, DV-
dc.date.accessioned2016-03-31T08:23:15Z-
dc.date.available2016-03-31T08:23:15Z-
dc.date.created2013-12-19-
dc.date.issued2009-05-
dc.identifier.issn0022-1139-
dc.identifier.other2009-OAK-0000028462-
dc.identifier.urihttps://oasis.postech.ac.kr/handle/2014.oak/15190-
dc.description.abstractNeat cinnamyl fluoride, geranyl fluoride, 5-carbomethoxy-3-fluorocyclohexene and parent 3-fluorocyclohexerre undergo spontaneous decomposition on contact with borosilicate glass or catalytic quantities of moderately strong acids that consists in polycondensation with elimination of HF initiated by electrophilic abstraction of F-. Acid sensitivity of these allylic fluorides correlates with stability of respective allylic cations, exceeds that of parent benzyl fluoride, yet can be mitigated by the use of Teflon and PFA containers that permit their isolation and handling in the neat state. (C) 2009 Elsevier B.V. All rights reserved.-
dc.description.statementofresponsibilityX-
dc.languageEnglish-
dc.publisherElsevier-
dc.relation.isPartOfJOURNAL OF FLUORINE CHEMISTRY-
dc.subjectCinnamyl fluoride-
dc.subjectGeranyl fluoride-
dc.subjectCyclohexenyl fluoride-
dc.subjectAllylic fluorides-
dc.subjectGlass-mediated decomposition-
dc.subjectSTEREOCONTROLLED SYNTHESIS-
dc.subjectENANTIOSELECTIVE SYNTHESIS-
dc.subjectMAGNETIC-RESONANCE-
dc.subjectHYDROGEN-FLUORIDE-
dc.subjectCARBOXYLIC-ACIDS-
dc.subjectBENZYL FLUORIDE-
dc.subjectMILD CONDITIONS-
dc.subjectALKYL FLUORIDE-
dc.subjectALCOHOLS-
dc.subjectFLUORINATION-
dc.titleOn the Isolation of Neat Allylic Fluorides-
dc.typeArticle-
dc.contributor.college화학과-
dc.identifier.doi10.1016/J.JFLUCHEM.2009.02.012-
dc.author.googleLee, E-
dc.author.googleYandulov, DV-
dc.relation.volume130-
dc.relation.issue5-
dc.relation.startpage474-
dc.relation.lastpage483-
dc.contributor.id10145005-
dc.relation.journalJOURNAL OF FLUORINE CHEMISTRY-
dc.relation.indexSCI급, SCOPUS 등재논문-
dc.relation.sciSCI-
dc.collections.nameJournal Papers-
dc.type.rimsART-
dc.identifier.bibliographicCitationJOURNAL OF FLUORINE CHEMISTRY, v.130, no.5, pp.474 - 483-
dc.identifier.wosid000266953500005-
dc.date.tcdate2019-01-01-
dc.citation.endPage483-
dc.citation.number5-
dc.citation.startPage474-
dc.citation.titleJOURNAL OF FLUORINE CHEMISTRY-
dc.citation.volume130-
dc.contributor.affiliatedAuthorLee, E-
dc.identifier.scopusid2-s2.0-67349246225-
dc.description.journalClass1-
dc.description.journalClass1-
dc.description.wostc13-
dc.description.scptc12*
dc.date.scptcdate2018-05-121*
dc.type.docTypeArticle-
dc.subject.keywordPlusSTEREOCONTROLLED SYNTHESIS-
dc.subject.keywordPlusENANTIOSELECTIVE SYNTHESIS-
dc.subject.keywordPlusMAGNETIC-RESONANCE-
dc.subject.keywordPlusHYDROGEN-FLUORIDE-
dc.subject.keywordPlusCARBOXYLIC-ACIDS-
dc.subject.keywordPlusBENZYL FLUORIDE-
dc.subject.keywordPlusMILD CONDITIONS-
dc.subject.keywordPlusALKYL FLUORIDE-
dc.subject.keywordPlusALCOHOLS-
dc.subject.keywordPlusFLUORINATION-
dc.subject.keywordAuthorCinnamyl fluoride-
dc.subject.keywordAuthorGeranyl fluoride-
dc.subject.keywordAuthorCyclohexenyl fluoride-
dc.subject.keywordAuthorAllylic fluorides-
dc.subject.keywordAuthorGlass-mediated decomposition-
dc.relation.journalWebOfScienceCategoryChemistry, Inorganic & Nuclear-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-

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Dept of Chemistry
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