DC Field | Value | Language |
---|---|---|
dc.contributor.author | Moon Chan Hwang | - |
dc.contributor.author | Jae-Wan Jang | - |
dc.contributor.author | Tae Kyu An | - |
dc.contributor.author | Park, CE | - |
dc.contributor.author | Yun-Hi Kim | - |
dc.contributor.author | Soon-Ki Kwon | - |
dc.date.accessioned | 2016-03-31T08:33:12Z | - |
dc.date.available | 2016-03-31T08:33:12Z | - |
dc.date.created | 2013-04-15 | - |
dc.date.issued | 2012-06-12 | - |
dc.identifier.issn | 0024-9297 | - |
dc.identifier.other | 2012-OAK-0000027489 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/15564 | - |
dc.description.abstract | A series of new p-type polymers, PNDT-T and PNDT-TT, with enforced coplanar structure for effective pi-electron delocalization, having naphtho[2,1-b:3,4-b']-dithiophene and thiophenes as main core units, were successfully synthesized by Stille coupling reaction. The naphtho[2,1-b:3,4-b']dithiophene unit of the polymer main chain enhances charge carrier mobility by extending pi-conjugation length and rigidly enforced coplanar structure. Both polymers, PNDT-T and PNDT-TT, have high thermal stability up to 250 degrees C with a high T-g of 402 degrees C. On the basis of AFM and XRD results, it was found that PNDT-TT showed relatively more highly ordered intermolecular structures than did PNDT-T, with thiophene unit and high field-effect mobility, because the bithiophene unit provides crystallinity with increasing planarity and enough space for interdigitation of the long alkyl side chains for high order. These new p-type polymers PNDT-T and PNDT-TT exhibit high carrier mobilities of 0.01 and 0.076 cm(2)/(V s) and on/off ratios of 4 x 10(5) and 7 x 10(6), respectively. The above results indicate that the plate structure with a sulfur-containing fully aromatic system, which has the upper direction extended, could enhance the thermal stability and charge transport characteristics for OTFT applications. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.relation.isPartOf | Macromolecules | - |
dc.subject | FIELD-EFFECT TRANSISTORS | - |
dc.subject | SOLAR-CELLS | - |
dc.subject | SEMICONDUCTING POLYMERS | - |
dc.subject | HIGH-MOBILITY | - |
dc.subject | CYCLIZATION | - |
dc.subject | COPOLYMERS | - |
dc.subject | MORPHOLOGY | - |
dc.subject | STABILITY | - |
dc.subject | STRATEGY | - |
dc.subject | ELECTRON | - |
dc.title | Synthesis and Characterization of New Thermally Stable Poly(naphthodithiophene) Derivatives and Applications for High Performance Organic Thin Film Transistors | - |
dc.type | Article | - |
dc.contributor.college | 화학공학과 | - |
dc.identifier.doi | 10.1021/MA300540F | - |
dc.author.google | Hwang, MC | - |
dc.author.google | Jang, JW | - |
dc.author.google | An, TK | - |
dc.author.google | Park, CE | - |
dc.author.google | Kim, YH | - |
dc.author.google | Kwon, SK | - |
dc.relation.volume | 45 | - |
dc.relation.issue | 11 | - |
dc.relation.startpage | 4520 | - |
dc.relation.lastpage | 4528 | - |
dc.contributor.id | 10104044 | - |
dc.relation.journal | Macromolecules | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | Macromolecules, v.45, no.11, pp.4520 - 4528 | - |
dc.identifier.wosid | 000305092200012 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 4528 | - |
dc.citation.number | 11 | - |
dc.citation.startPage | 4520 | - |
dc.citation.title | Macromolecules | - |
dc.citation.volume | 45 | - |
dc.contributor.affiliatedAuthor | Park, CE | - |
dc.identifier.scopusid | 2-s2.0-84862196765 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 25 | - |
dc.description.scptc | 26 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article | - |
dc.subject.keywordPlus | HIGH-MOBILITY | - |
dc.subject.keywordPlus | SEMICONDUCTING POLYMERS | - |
dc.subject.keywordPlus | COPOLYMERS | - |
dc.subject.keywordPlus | MORPHOLOGY | - |
dc.subject.keywordPlus | STRATEGY | - |
dc.subject.keywordPlus | ELECTRON | - |
dc.subject.keywordPlus | DESIGN | - |
dc.relation.journalWebOfScienceCategory | Polymer Science | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Polymer Science | - |
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