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Tunable Nanoporous Network Polymer Nanocomposites having Size-Selective Ion Transfer for Dye-sensitized Solar Cells SCIE SCOPUS

Title
Tunable Nanoporous Network Polymer Nanocomposites having Size-Selective Ion Transfer for Dye-sensitized Solar Cells
Authors
Sung-Hae ParkJongchul LimYoung Soo KwonIn Young SongJong Min ChoiSeulki SongPark, T
Date Issued
2013-02
Publisher
Wiley
Abstract
Nanoporous network polymer nanocomposites with tunable pore size for size-dependent selective ion transport are successfully prepared via the surface-induced cross-linking polymerization of methyl methacrylate (MMA) and 1,6-hexanediol diacrylate (HDDA) on the surfaces of nanocrystalline TiO2 particles. The morphologies of the porous network polymer layer and nanopores were investigated by transmission electron microscopy (TEM), field emission scanning electron microscopy (FE-SEM), and BrunauerEmmettTeller (BET) experiments. The porous layer size-selectively screened the ions that contacted the nanocrystalline TiO2 particles, as demonstrated by ion conductivity measurements, electrochemical impedance spectroscopy (EIS), and transient absorption spectroscopy (TAS).
Keywords
size-selective ion transfer; dye-senistised solar cells; tunable nanoporosity; retardation of recombination; long-term stability; HOLE TRANSPORT MATERIAL; CHARGE RECOMBINATION; PHOTOVOLTAIC PERFORMANCE; HIGH-EFFICIENCY; TIO2 FILMS; THIN-FILM; LOW-COST; ELECTROLYTES; ELECTRODES; HETEROJUNCTIONS
URI
https://oasis.postech.ac.kr/handle/2014.oak/15688
DOI
10.1002/AENM.201200437
ISSN
1614-6832
Article Type
Article
Citation
Advanced Energy Materials, vol. 3, no. 2, page. 184 - 192, 2013-02
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박태호PARK, TAIHO
Dept. of Chemical Enginrg
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