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Highly Efficient and Chemoselective Ruthenium-Catalyzed Hydrosilylation of Aldehydes SCIE SCOPUS

Title
Highly Efficient and Chemoselective Ruthenium-Catalyzed Hydrosilylation of Aldehydes
Authors
Do, YHan, JYoung Ho RheePark, J
Date Issued
2011-12
Publisher
WILEY-BLACKWELL
Abstract
The highly chemoselective hydrosilylation of aldehydes was achieved using a ruthenium catalyst activated by a household fluorescent light (30 W) at or below room temperature. The hydrosilylation was almost exclusive to aldehydes over ketones and olefins.
Keywords
aldehydes; chemoselectivity; hydrosilylation; photochemistry; ruthenium complexes; DYNAMIC KINETIC RESOLUTION; BOWL-SHAPED PHOSPHANE; RACEMIZATION CATALYST; SECONDARY ALCOHOLS; CARBONYL-COMPOUNDS; HINDERED KETONES; RATE ENHANCEMENT; COMPLEXES; LIGAND; CONVENIENT
URI
https://oasis.postech.ac.kr/handle/2014.oak/16818
DOI
10.1002/ADSC.201100426
ISSN
1615-4150
Article Type
Article
Citation
ADVANCED SYNTHESIS & CATALYSIS, vol. 353, no. 18, page. 3363 - 3366, 2011-12
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