DC Field | Value | Language |
---|---|---|
dc.contributor.author | Shimonishi, Y | - |
dc.contributor.author | Zhang, T | - |
dc.contributor.author | Imanishi, N | - |
dc.contributor.author | Im, D | - |
dc.contributor.author | Lee, DJ | - |
dc.contributor.author | Hirano, A | - |
dc.contributor.author | Takeda, Y | - |
dc.contributor.author | Yamamoto, O | - |
dc.contributor.author | Sammes, N | - |
dc.date.accessioned | 2016-03-31T09:14:13Z | - |
dc.date.available | 2016-03-31T09:14:13Z | - |
dc.date.created | 2012-02-10 | - |
dc.date.issued | 2011-06-01 | - |
dc.identifier.issn | 0378-7753 | - |
dc.identifier.other | 2011-OAK-0000024711 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/16867 | - |
dc.description.abstract | The stability of the high lithium ion conducting glass ceramics, Li1+x+yTi2-xAlxSiyP3-yO12 (LTAP) in alkaline aqueous solutions with and without LiCl has been examined. A significant conductivity decrease of the LTAP plate immersed in 0.057 M LiOH aqueous solution at 50 degrees C for 3 weeks was observed. However, no conductivity change of the LTAP plate immersed in LiCl saturated LiOH aqueous solutions at 50 degrees C for 3 weeks was observed. The pH value of the LiCl-LiOH-H2O solution with saturated LiCl was in a range of 7-9. The molarity of LiOH and LiCl in the LiOH and LiCl saturated aqueous solution were estimated to be 5.12 and 11.57 M, respectively, by analysis of Li+ and OH-. The high concentration of LiOH and the low pH value of 8.14 in this solution suggested that the dissociation of LiON into Li+ and OH- is too low in the solution with a high concentration of Li+. These results suggest that the water stable LTAP could be used as a protect layer of the lithium metal anode in the lithium/air cell with LiCl saturated aqueous solution as the electrolyte, because the content of OH- ions in the LiCl saturated aqueous solution does not increase via the cell reaction of Li + 1/2O(2) + H2O -> 2LiOH, and LTAP is stable under a deep discharge state. (C) 2011 Elsevier B.V. All rights reserved. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | ELSEVIER SCIENCE BV | - |
dc.relation.isPartOf | JOURNAL OF POWER SOURCES | - |
dc.subject | Lithium/air battery | - |
dc.subject | Solid electrolyte | - |
dc.subject | Anode | - |
dc.subject | Alkaline solution | - |
dc.subject | GLASS-CERAMICS | - |
dc.title | A study on lithium/air secondary batteries-Stability of the NASICON-type lithium ion conducting solid electrolyte in alkaline aqueous solutions | - |
dc.type | Article | - |
dc.contributor.college | 화학공학과 | - |
dc.identifier.doi | 10.1016/J.JPOWSOUR.2011.02.023 | - |
dc.author.google | Shimonishi, Y | - |
dc.author.google | Zhang, T | - |
dc.author.google | Imanishi, N | - |
dc.author.google | Im, D | - |
dc.author.google | Lee, DJ | - |
dc.author.google | Hirano, A | - |
dc.author.google | Takeda, Y | - |
dc.author.google | Yamamoto, O | - |
dc.author.google | Sammes, N | - |
dc.relation.volume | 196 | - |
dc.relation.issue | 11 | - |
dc.relation.startpage | 5128 | - |
dc.relation.lastpage | 5132 | - |
dc.contributor.id | 10978306 | - |
dc.relation.journal | JOURNAL OF POWER SOURCES | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | JOURNAL OF POWER SOURCES, v.196, no.11, pp.5128 - 5132 | - |
dc.identifier.wosid | 000289599900034 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 5132 | - |
dc.citation.number | 11 | - |
dc.citation.startPage | 5128 | - |
dc.citation.title | JOURNAL OF POWER SOURCES | - |
dc.citation.volume | 196 | - |
dc.contributor.affiliatedAuthor | Sammes, N | - |
dc.identifier.scopusid | 2-s2.0-79952992200 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 99 | - |
dc.description.scptc | 94 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article | - |
dc.subject.keywordAuthor | Lithium/air battery | - |
dc.subject.keywordAuthor | Solid electrolyte | - |
dc.subject.keywordAuthor | Anode | - |
dc.subject.keywordAuthor | Alkaline solution | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Electrochemistry | - |
dc.relation.journalWebOfScienceCategory | Energy & Fuels | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Electrochemistry | - |
dc.relation.journalResearchArea | Energy & Fuels | - |
dc.relation.journalResearchArea | Materials Science | - |
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