DC Field | Value | Language |
---|---|---|
dc.contributor.author | 문식원 | en_US |
dc.date.accessioned | 2014-12-01T11:48:34Z | - |
dc.date.available | 2014-12-01T11:48:34Z | - |
dc.date.issued | 2013 | en_US |
dc.identifier.other | OAK-2014-01306 | en_US |
dc.identifier.uri | http://postech.dcollection.net/jsp/common/DcLoOrgPer.jsp?sItemId=000001557801 | en_US |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/1808 | - |
dc.description | Doctor | en_US |
dc.description.abstract | Poly(ethylene oxide) (PEO) films with uniform nanopatterns were prepared by spin-coating aged dilute solutions containing crystallized precursors. To prepare the crystallized precursors of PEO in toluene, a PEO solution was heated at 70°C for 20 min and incubated at 18°C for 6 hours. The crystallized precursors in the solution were metastable and had a fibrillar morphology that deformed during the spin-coating process. The spin-coating conditions required to obtain a uniformly striped nanopattern were: a spin speed between 2000 and 4000 rpm and a PEO mass fraction in the range 0.2–0.4 wt%. Blocky PEO stripes formed from flat-on lamellar crystals (the chain axis was perpendicular to the substrate) were 10 nm thick, 100 nm wide, and 50 µm long and were arranged in periodic stacks with a period of 200 nm in one direction over a 50 × 50 µm2 area on a silicon wafer. Dense arrangement of the PEO stripes on the silicon wafer during spin-coating produced a grain boundary line in the shape of a distorted hexagonal closed curve (DHCC) on the centimeter length scale. In the DHCC, uniform nanopatterns composed of blocky fibers formed a radial pattern that spread out from a point in the middle of the DHCC to the grain boundary line. | en_US |
dc.language | eng | en_US |
dc.publisher | 포항공과대학교 | en_US |
dc.rights | BY_NC_ND | en_US |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/2.0/kr | en_US |
dc.title | 용액에서 결정화된 전구체를 이용한 폴리에틸렌 옥사이드 나노 패턴의 박막 제조 | en_US |
dc.title.alternative | Fabrication of Nanopatterned Poly(ethylene oxide) Thin Films Prepared from Precursors Crystallized in Solution | en_US |
dc.type | Thesis | en_US |
dc.contributor.college | 일반대학원 신소재공학과 | en_US |
dc.date.degree | 2013- 2 | en_US |
dc.type.docType | Thesis | - |
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