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A practical diastereoselective synthesis of beta-amino-alpha-hydroxy carboxylates SCIE SCOPUS
- Title
- A practical diastereoselective synthesis of beta-amino-alpha-hydroxy carboxylates
- Date Issued
- 2003-11-28
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Abstract
- Practical synthetic routes to beta-amino-alpha-hydroxy carboxylates (AHC) have been developed from amino acids. Reduction of beta-amino-alpha-keto esters 6 with NaBH4 was found to give anti-AHCs 7 in high de, which were efficiently converted to the corresponding syn-AHCs 8 via oxazolidine ring 10 formation. (C) 2003 Elsevier Ltd. All rights reserved.
- Keywords
- C-13 SIDE-CHAIN; STEREOSELECTIVE SYNTHESIS; CHEMOENZYMATIC SYNTHESIS; ASYMMETRIC-SYNTHESIS; TAXOL; TAXOTERE; INHIBITOR; CHEMISTRY; ESTERS; ACID
- ISSN
- 0957-4166
- Article Type
- Article
- Citation
- TETRAHEDRON-ASYMMETRY, vol. 14, no. 23, page. 3639 - 3641, 2003-11-28
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