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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Park, ED | - |
| dc.contributor.author | Hwang, YS | - |
| dc.contributor.author | Lee, CW | - |
| dc.contributor.author | Lee, JS | - |
| dc.date.accessioned | 2016-03-31T12:47:51Z | - |
| dc.date.available | 2016-03-31T12:47:51Z | - |
| dc.date.created | 2009-02-28 | - |
| dc.date.issued | 2003-07-25 | - |
| dc.identifier.issn | 0926-860X | - |
| dc.identifier.other | 2003-OAK-0000003564 | - |
| dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/18422 | - |
| dc.description.abstract | Copper- and vanadium-catalyzed oxidation of methane into methyl trifluoroacetate and formic acid with in situ generated H2O2 from H-2 and O-2 over Pd/C was investigated in trifluoroacetic acid (TFA) and/or trifluoroacetic anhydride (TFAA) as a solvent. Metallic palladium was responsible for the in situ generation of hydrogen peroxide from dihydrogen and dioxygen. Divalent copper hydroperoxide and monoperoxomonovanadate, VO(O-2)(+), seemed to be related to C-H bond activation. The radical chain reaction did not occur in either copper- or vanadium-catalyzed methane oxidation. However, methyl radical appeared to be produced in vanadium system but not in copper system. (C) 2003 Elsevier Science B.V. All rights reserved. | - |
| dc.description.statementofresponsibility | X | - |
| dc.language | English | - |
| dc.publisher | ELSEVIER SCIENCE BV | - |
| dc.relation.isPartOf | APPLIED CATALYSIS A-GENERAL | - |
| dc.subject | methane oxidation | - |
| dc.subject | methanol | - |
| dc.subject | Pd/C | - |
| dc.subject | copper | - |
| dc.subject | vanadium | - |
| dc.subject | XAFS | - |
| dc.subject | ACETIC-ACID SYNTHESIS | - |
| dc.subject | C-H BONDS | - |
| dc.subject | HYDROGEN-PEROXIDE | - |
| dc.subject | 11-MOLYBDO-1-VANADOPHOSPHORIC ACID | - |
| dc.subject | METHYL TRIFLUOROACETATE | - |
| dc.subject | SELECTIVE OXIDATION | - |
| dc.subject | BIMETALLIC SYSTEM | - |
| dc.subject | PHASE OXIDATION | - |
| dc.subject | CARBON-MONOXIDE | - |
| dc.subject | LOW-TEMPERATURE | - |
| dc.title | Copper- and vanadium-catalyzed methane oxidation into oxygenates with in situ generated H2O2 over Pd/C | - |
| dc.type | Article | - |
| dc.contributor.college | 화학공학과 | - |
| dc.identifier.doi | 10.1016/S0926-860X(0 | - |
| dc.author.google | Park, ED | - |
| dc.author.google | Hwang, YS | - |
| dc.author.google | Lee, CW | - |
| dc.author.google | Lee, JS | - |
| dc.relation.volume | 247 | - |
| dc.relation.issue | 2 | - |
| dc.relation.startpage | 269 | - |
| dc.relation.lastpage | 281 | - |
| dc.contributor.id | 10087281 | - |
| dc.relation.journal | APPLIED CATALYSIS A-GENERAL | - |
| dc.relation.index | SCI급, SCOPUS 등재논문 | - |
| dc.relation.sci | SCI | - |
| dc.collections.name | Journal Papers | - |
| dc.type.rims | ART | - |
| dc.identifier.bibliographicCitation | APPLIED CATALYSIS A-GENERAL, v.247, no.2, pp.269 - 281 | - |
| dc.identifier.wosid | 000184520300008 | - |
| dc.date.tcdate | 2019-01-01 | - |
| dc.citation.endPage | 281 | - |
| dc.citation.number | 2 | - |
| dc.citation.startPage | 269 | - |
| dc.citation.title | APPLIED CATALYSIS A-GENERAL | - |
| dc.citation.volume | 247 | - |
| dc.contributor.affiliatedAuthor | Lee, JS | - |
| dc.identifier.scopusid | 2-s2.0-0038374169 | - |
| dc.description.journalClass | 1 | - |
| dc.description.journalClass | 1 | - |
| dc.description.wostc | 29 | - |
| dc.type.docType | Article | - |
| dc.subject.keywordPlus | ACETIC-ACID SYNTHESIS | - |
| dc.subject.keywordPlus | C-H BONDS | - |
| dc.subject.keywordPlus | 11-MOLYBDO-1-VANADOPHOSPHORIC ACID | - |
| dc.subject.keywordPlus | SELECTIVE OXIDATION | - |
| dc.subject.keywordPlus | BIMETALLIC SYSTEM | - |
| dc.subject.keywordPlus | PHASE OXIDATION | - |
| dc.subject.keywordPlus | LOW-TEMPERATURE | - |
| dc.subject.keywordPlus | ALKANES | - |
| dc.subject.keywordPlus | ETHANE | - |
| dc.subject.keywordPlus | FUNCTIONALIZATION | - |
| dc.subject.keywordAuthor | methane oxidation | - |
| dc.subject.keywordAuthor | methanol | - |
| dc.subject.keywordAuthor | Pd/C | - |
| dc.subject.keywordAuthor | copper | - |
| dc.subject.keywordAuthor | vanadium | - |
| dc.subject.keywordAuthor | XAFS | - |
| dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
| dc.relation.journalWebOfScienceCategory | Environmental Sciences | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
| dc.relation.journalResearchArea | Chemistry | - |
| dc.relation.journalResearchArea | Environmental Sciences & Ecology | - |
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