New fluorescent photoinduced electron transfer chemosensor for the recognition of H2PO4-

Abstract

The fluorescent chemosensor 1 bearing two imidazolium groups at the 1,8-position of anthracene has been designed for the recognition of anions through the (C-H)(+)---X- hydrogen bond formation. As unique tweezer-like binding of 1 with anions is predicted by the ab initio calculations, strong anion-binding properties of chemosensor 1 are demonstrated by using fluorescence as well as H-1 NMR.