DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, S | - |
dc.contributor.author | Koh, JH | - |
dc.contributor.author | Park, J | - |
dc.date.accessioned | 2016-03-31T13:11:43Z | - |
dc.date.available | 2016-03-31T13:11:43Z | - |
dc.date.created | 2009-03-16 | - |
dc.date.issued | 2001-12-03 | - |
dc.identifier.issn | 0022-328X | - |
dc.identifier.other | 2001-OAK-0000002365 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/19281 | - |
dc.description.abstract | ortho-Silylation of chiral 2,2'-bis(oxazolinyl)-1,1'-bis(diphenylphosphino)ferrocenes (1) provided monosilylated derivatives, which were employed as chiral ligands in the Pd-catalyzed asymmetric allylic alkylation of 1,3-diphenylprop-2-enyl acetate with dimethyl malonate. The major product has (S)-configuration in the reactions employing three diastereomers 1 and the monosilylated ligand derived from the (S,S,S-P,S-P)-diastereomer (up to 99% ee). In sharp contrast, the enantioselectivity was reversed to give (R)-product in the reactions with the ligands derived from the (S,S,R-P,R-P)-diastereomer (up to 96% ee). (C) 2001 Elsevier Science B.V. All rights reserved. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.relation.isPartOf | JOURNAL OF ORGANOMETALLIC CHEMISTRY | - |
dc.subject | catalysis | - |
dc.subject | palladium | - |
dc.subject | ferrocene | - |
dc.subject | silylation | - |
dc.subject | enantioselectivity | - |
dc.subject | CHIRAL 1,1&apos | - |
dc.subject | -BIS(OXAZOLINYL)FERROCENES | - |
dc.subject | LIGANDS | - |
dc.subject | LITHIATION | - |
dc.subject | OXAZOLINYLFERROCENES | - |
dc.subject | ENANTIOSELECTIVITY | - |
dc.subject | SUBSTITUTION | - |
dc.subject | COMPLEXES | - |
dc.subject | BACKBONE | - |
dc.title | ortho-silylation of 2,2 '-bis(oxazolinyl)-1,1 '-bis(diphenylphosphino)ferrocenes and remarkable effect of the silyl groups on the enantio selectivity in Pd-catalyzed asymmetric allylic alkylation | - |
dc.type | Article | - |
dc.contributor.college | 화학과 | - |
dc.identifier.doi | 10.1016/S0022-328X(01)00877-4 | - |
dc.author.google | Lee, S | - |
dc.author.google | Koh, JH | - |
dc.author.google | Park, J | - |
dc.relation.volume | 637 | - |
dc.relation.startpage | 99 | - |
dc.relation.lastpage | 106 | - |
dc.contributor.id | 10075891 | - |
dc.relation.journal | JOURNAL OF ORGANOMETALLIC CHEMISTRY | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | JOURNAL OF ORGANOMETALLIC CHEMISTRY, v.637, pp.99 - 106 | - |
dc.identifier.wosid | 000172577800015 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 106 | - |
dc.citation.startPage | 99 | - |
dc.citation.title | JOURNAL OF ORGANOMETALLIC CHEMISTRY | - |
dc.citation.volume | 637 | - |
dc.contributor.affiliatedAuthor | Park, J | - |
dc.identifier.scopusid | 2-s2.0-0035803754 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 23 | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | CHIRAL 1,1&apos | - |
dc.subject.keywordPlus | -BIS(OXAZOLINYL)FERROCENES | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordPlus | LITHIATION | - |
dc.subject.keywordPlus | OXAZOLINYLFERROCENES | - |
dc.subject.keywordPlus | ENANTIOSELECTIVITY | - |
dc.subject.keywordPlus | SUBSTITUTION | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | BACKBONE | - |
dc.subject.keywordAuthor | catalysis | - |
dc.subject.keywordAuthor | palladium | - |
dc.subject.keywordAuthor | ferrocene | - |
dc.subject.keywordAuthor | silylation | - |
dc.subject.keywordAuthor | enantioselectivity | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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