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Reactions of (eta(5)-indenyl)Ru(PPh3)(2)Cl with CH2Cl2 and CHCl3: Formation of (eta(5)-indenyl)Ru{CH2PPh2(C6H4)}(PBh(3)) and (eta(5)-indenyl) Ru(PPh3)(CO)Cl SCIE SCOPUS
- Title
- Reactions of (eta(5)-indenyl)Ru(PPh3)(2)Cl with CH2Cl2 and CHCl3: Formation of (eta(5)-indenyl)Ru{CH2PPh2(C6H4)}(PBh(3)) and (eta(5)-indenyl) Ru(PPh3)(CO)Cl
- Date Issued
- 2001-04-30
- Publisher
- AMER CHEMICAL SOC
- Abstract
- A cyclic phoshorus ylide complex, (eta (5)-indenyl)Ru{CH2PPh2(C6H4)}(PPh3) (2), and (eta (5)-indenyl)Ru(PPh3)(CO)Cl (3) were formed in the reactions of (eta (5)-indenyl)Ru(PPh3)(2)Cl (1) with CH2Cl2 and CHCl3 in the presence of KOH and 2-propanol, respectively.
- Keywords
- TERMINAL METHYLENE COMPLEX; RUTHENIUM COMPLEXES; SECONDARY ALCOHOLS; PHOSPHORUS YLIDES; CRYSTAL-STRUCTURE; DICHLOROMETHANE; RACEMIZATION; IRIDIUM(I); ACTIVATION
- ISSN
- 0276-7333
- Article Type
- Article
- Citation
- ORGANOMETALLICS, vol. 20, no. 9, page. 1892 - 1894, 2001-04-30
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Related Researcher
- 박재욱PARK, JAIWOOK
- Dept of Chemistry