DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kang, SG | - |
dc.contributor.author | Song, J | - |
dc.contributor.author | Whang, D | - |
dc.contributor.author | Kim, K | - |
dc.date.accessioned | 2016-03-31T13:25:13Z | - |
dc.date.available | 2016-03-31T13:25:13Z | - |
dc.date.created | 2009-03-20 | - |
dc.date.issued | 2000-11-20 | - |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.other | 2000-OAK-0000001641 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/19785 | - |
dc.description.abstract | New 14-membered tetraaza macrocycles 1,8-diallyl-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane (L-2) and 1,8-bis(n-propyl)-3,5,7,7,10,12,14,14-octamethyl-1,4,8,1.1-tetraazacyclotctradecane (L-3) have been prepared by direct reaction of 2,5,5,7,9,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradecane (L-1) with allyl bromide or n-propyl bromide. The nickel(II) and copper(II) complexes of L-2 and L-3 have been prepared. The macrocycles show high copper(II) selectivity against nickel(II) ion in methanol solutions containing water. The wavelengths (ca. 505 nm) of the d-d bands for the nickel(II) complexes are extraordinarily longer than those for the complexes of L-1 and other related di N-alkylated 14-membered tetraaza macrocycles. Crystal structure of [NiL2](ClO4)(2) shows that the average Ni-N bond distance (1.992 Angstrom) of the complex is distinctly longer than those of other related nickel(II) complexes. Effects of the N- and C-substituents on the properties of the macrocyclic compounds are discussed. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | KOREAN CHEMICAL SOC | - |
dc.relation.isPartOf | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.subject | CYCLOHEXANE RINGS | - |
dc.subject | AQUEOUS-SOLUTIONS | - |
dc.subject | CRYSTAL-STRUCTURE | - |
dc.subject | LIGANDS | - |
dc.subject | STABILIZATION | - |
dc.subject | METHYLATION | - |
dc.subject | PROTONATION | - |
dc.subject | SELECTIVITY | - |
dc.subject | CYCLAM | - |
dc.subject | IONS | - |
dc.title | Preparation and properties of new Di-N-alkylated 14-membered tetraaza macrocycles and their nickel(II) and copper(II) complexes | - |
dc.type | Article | - |
dc.contributor.college | 화학과 | - |
dc.author.google | Kang, SG | - |
dc.author.google | Song, J | - |
dc.author.google | Whang, D | - |
dc.author.google | Kim, K | - |
dc.relation.volume | 21 | - |
dc.relation.issue | 11 | - |
dc.relation.startpage | 1106 | - |
dc.relation.lastpage | 1110 | - |
dc.contributor.id | 10104366 | - |
dc.relation.journal | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.21, no.11, pp.1106 - 1110 | - |
dc.identifier.wosid | 000165498400013 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 1110 | - |
dc.citation.number | 11 | - |
dc.citation.startPage | 1106 | - |
dc.citation.title | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.citation.volume | 21 | - |
dc.contributor.affiliatedAuthor | Kim, K | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 5 | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | CYCLOHEXANE RINGS | - |
dc.subject.keywordPlus | AQUEOUS-SOLUTIONS | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordPlus | STABILIZATION | - |
dc.subject.keywordPlus | METHYLATION | - |
dc.subject.keywordPlus | PROTONATION | - |
dc.subject.keywordPlus | SELECTIVITY | - |
dc.subject.keywordPlus | CYCLAM | - |
dc.subject.keywordPlus | IONS | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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