DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jeon, YM | - |
dc.contributor.author | Heo, J | - |
dc.contributor.author | Lee, WM | - |
dc.contributor.author | Chang, TH | - |
dc.contributor.author | Kim, K | - |
dc.date.accessioned | 2016-03-31T13:37:40Z | - |
dc.date.available | 2016-03-31T13:37:40Z | - |
dc.date.created | 2009-03-19 | - |
dc.date.issued | 1999-09-27 | - |
dc.identifier.issn | 0276-7333 | - |
dc.identifier.other | 1999-OAK-0000000975 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/20248 | - |
dc.description.abstract | Using the disymmetric N,N'-bis(trimethylsilyl)aminobenzylamine (H(2)MABA; 1) ligand, the new group 4 metal complexes (MABA)TiCl2 (2), (MABA)TiMe2 (3), (MABA)Ti(CH2Ph)(2) (4), (MABA)ZrCl2 (5), and (MABA)(2)Zr (6) were prepared. X-ray crystal structures of 2, 4, and 6 were determined. The crystal structure of 2 suggests that an agostic interaction between the titanium metal center and benzylic protons exists in the solid state. However, the agostic interaction is not sustained in solution, as indicated by NMR spectroscopy. Complexes 2 and 5, activated by MMAO, and 4, activated by B(C6F5)(3), have moderate catalytic activities for the polymerization of alpha-olefins. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.relation.isPartOf | ORGANOMETALLICS | - |
dc.subject | LIVING POLYMERIZATION | - |
dc.subject | AGOSTIC INTERACTIONS | - |
dc.subject | MOLECULAR-STRUCTURE | - |
dc.subject | CRYSTAL-STRUCTURES | - |
dc.subject | SIGMA-BONDS | - |
dc.subject | CATALYSTS | - |
dc.subject | CONTAIN | - |
dc.subject | DERIVATIVES | - |
dc.subject | CHEMISTRY | - |
dc.subject | ALKENE | - |
dc.title | Titanium and zirconium complexes with the new ancillary diamido ligand N,N '-bis(trimethylsilyl)amidobenzylamido(2-): Syntheses, structures, and alpha-olefin polymerization activities | - |
dc.type | Article | - |
dc.contributor.college | 화학과 | - |
dc.identifier.doi | 10.1021/om990121b | - |
dc.author.google | Jeon, YM | - |
dc.author.google | Heo, J | - |
dc.author.google | Lee, WM | - |
dc.author.google | Chang, TH | - |
dc.author.google | Kim, K | - |
dc.relation.volume | 18 | - |
dc.relation.issue | 20 | - |
dc.relation.startpage | 4107 | - |
dc.relation.lastpage | 4113 | - |
dc.contributor.id | 10104366 | - |
dc.relation.journal | ORGANOMETALLICS | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | ORGANOMETALLICS, v.18, no.20, pp.4107 - 4113 | - |
dc.identifier.wosid | 000083033500025 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 4113 | - |
dc.citation.number | 20 | - |
dc.citation.startPage | 4107 | - |
dc.citation.title | ORGANOMETALLICS | - |
dc.citation.volume | 18 | - |
dc.contributor.affiliatedAuthor | Chang, TH | - |
dc.contributor.affiliatedAuthor | Kim, K | - |
dc.identifier.scopusid | 2-s2.0-0001323442 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 36 | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | LIVING POLYMERIZATION | - |
dc.subject.keywordPlus | AGOSTIC INTERACTIONS | - |
dc.subject.keywordPlus | MOLECULAR-STRUCTURE | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURES | - |
dc.subject.keywordPlus | SIGMA-BONDS | - |
dc.subject.keywordPlus | CATALYSTS | - |
dc.subject.keywordPlus | CONTAIN | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | ALKENE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
library@postech.ac.kr Tel: 054-279-2548
Copyrights © by 2017 Pohang University of Science ad Technology All right reserved.