Practical synthesis of all inositol stereoisomers from myo-inositol
SCIE
SCOPUS
- Title
- Practical synthesis of all inositol stereoisomers from myo-inositol
- Authors
- Chung, SK; Kwon, YU
- Date Issued
- 1999-08-02
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Abstract
- Synthesis of six inositol stereoisomers was successfully carried out via conduritol intermediates prepared from myo-inositol. Dihydroxylation and epoxidation followed by ring opening of the conduritol B, C and F derivatives gave epi-, allo-, muco-, neo-, DL-chiro- and scyllo-inositol. The cis-inositol derivative, which may not be prepared by this approach, was synthesized in 5 steps via 2-O-benzoyl-myo-inositol orthoformate as the key intermediate. (C) 1999 Elsevier Science Ltd. All rights reserved.
- Keywords
- POSSIBLE REGIOISOMERS; CHIRO-INOSITOL; VICINAL DIOLS; CARBOHYDRATE-CHEMISTRY; ALLYL GROUP; MYOINOSITOL; DERIVATIVES; OLEFINS; RECEPTOR; BINDING
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/20321
- DOI
- 10.1016/S0960-894X(99)00348-0
- ISSN
- 0960-894X
- Article Type
- Article
- Citation
- BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, vol. 9, no. 15, page. 2135 - 2140, 1999-08-02
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