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Cited 91 time in webofscience Cited 104 time in scopus
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dc.contributor.authorKoh, JH-
dc.contributor.authorJung, HM-
dc.contributor.authorKim, MJ-
dc.contributor.authorPark, J-
dc.date.accessioned2016-03-31T13:39:44Z-
dc.date.available2016-03-31T13:39:44Z-
dc.date.created2009-03-18-
dc.date.issued1999-08-20-
dc.identifier.issn0040-4039-
dc.identifier.other1999-OAK-0000000861-
dc.identifier.urihttps://oasis.postech.ac.kr/handle/2014.oak/20325-
dc.description.abstract(eta(5)-Indenyl)RuCl(PPh3)(2) was found to catalyze the racemization of secondary alcohols in the presence of triethylamine and oxygen. Unlike previously reported metal-catalyzed racemizations, ketones were not required as hydrogen mediators in our process. The Ru-catalyzed racemization was coupled with enzymatic acetylation for the dynamic kinetic resolution of secondary alcohols to give chiral acetates in good yields (60-98%) with high enantioselectivities (82-99% ee). (C) 1999 Elsevier Science Ltd. All rights reserved.-
dc.description.statementofresponsibilityX-
dc.languageEnglish-
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.relation.isPartOfTETRAHEDRON LETTERS-
dc.subjectDYNAMIC KINETIC RESOLUTION-
dc.subjectORGANIC-SYNTHESIS-
dc.titleEnzymatic resolution of secondary alcohols coupled with ruthenium-catalyzed racemization without hydrogen mediator-
dc.typeArticle-
dc.contributor.college화학과-
dc.identifier.doi10.1016/S0040-4039(99)01237-X-
dc.author.googleKoh, JH-
dc.author.googleJung, HM-
dc.author.googleKim, MJ-
dc.author.googlePark, J-
dc.relation.volume40-
dc.relation.issue34-
dc.relation.startpage6281-
dc.relation.lastpage6284-
dc.contributor.id10075891-
dc.relation.journalTETRAHEDRON LETTERS-
dc.relation.indexSCI급, SCOPUS 등재논문-
dc.relation.sciSCI-
dc.collections.nameJournal Papers-
dc.type.rimsART-
dc.identifier.bibliographicCitationTETRAHEDRON LETTERS, v.40, no.34, pp.6281 - 6284-
dc.identifier.wosid000081932200036-
dc.date.tcdate2019-01-01-
dc.citation.endPage6284-
dc.citation.number34-
dc.citation.startPage6281-
dc.citation.titleTETRAHEDRON LETTERS-
dc.citation.volume40-
dc.contributor.affiliatedAuthorKim, MJ-
dc.contributor.affiliatedAuthorPark, J-
dc.identifier.scopusid2-s2.0-0033588195-
dc.description.journalClass1-
dc.description.journalClass1-
dc.description.wostc86-
dc.type.docTypeArticle-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-

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김만주KIM, MAHN JOO
Dept of Chemistry
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