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Photocleavage coupling reactions between cyclohexa-2,4-dienone sulfone derivatives and amines by visible light irradiation SCIE SCOPUS
- Title
- Photocleavage coupling reactions between cyclohexa-2,4-dienone sulfone derivatives and amines by visible light irradiation
- Authors
- Kim, YM; Kwon, TW; Chung, SK; Barton, DHR
- Date Issued
- 1999-04-19
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Abstract
- A stable sulfone derivative of 2,4,6-trimethylcyclohexa-2,4-diene-1-one (7) undergoes facile ring cleavage under visible light to produce a ketene intermediate, which could be efficiently captured by amines to give amides even in the presence of competing nucleophiles such as water and ethanol. (C) 1999 Elsevier Science Ltd. All rights reserved.
- ISSN
- 0960-894X
- Article Type
- Article
- Citation
- BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, vol. 9, no. 8, page. 1175 - 1178, 1999-04-19
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