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A facile one step synthesis of ethyl 2-(1,1-dialkyl and arylmethyl) malonates SCIE SCOPUS
- Title
- A facile one step synthesis of ethyl 2-(1,1-dialkyl and arylmethyl) malonates
- Date Issued
- 1999-01
- Publisher
- MARCEL DEKKER INC
- Abstract
- Diethyl ethoxymethylenemalonate (EMME) is unexpectedly converted into diethyl 2-(1,1-dialkyl and diarylmethyl) malonate derivatives by a classical Grignard reaction. Addition of organocuprates to EMME gave diethyl 2-(1-ethoxyalkyl) malonate derivatives. The yields range from 42-63%.
- Keywords
- DERIVATIVES; ACIDS
- ISSN
- 0039-7911
- Article Type
- Article
- Citation
- SYNTHETIC COMMUNICATIONS, vol. 29, no. 2, page. 343 - 350, 1999-01
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