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Efficient catalytic racemization of secondary alcohols. SCIE SCOPUS

Title
Efficient catalytic racemization of secondary alcohols.
Authors
Koh, JHJeong, HMPark, J
Date Issued
1998-07-30
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Abstract
(eta(5)-Indenyl)RuCl(PPh3)(2) was found to efficiently catalyze the racemization of chiral alcohols such as (S)-1-phenylethan-1 -ol, (S)-1-phenylpropan-2-ol and (S)-4-phenylbutan-2-ol at room temperature in the presence of base. The catalytic activity of five other Ru(II) complexes was also investigated. The effects of varying reaction conditions such as reaction temperature, solvent, and base were investigated as well. (C) 1998 Elsevier Science Ltd. All rights reserved.
Keywords
racemization; alcohol; ruthenium; catalyst; INDENYL COMPLEXES; CYCLOPENTADIENYL; RUTHENIUM(II); KETONES
URI
https://oasis.postech.ac.kr/handle/2014.oak/20717
DOI
10.1016/S0040-4039(98)01116-2
ISSN
0040-4039
Article Type
Article
Citation
TETRAHEDRON LETTERS, vol. 39, no. 31, page. 5545 - 5548, 1998-07-30
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박재욱PARK, JAIWOOK
Dept of Chemistry
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