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Total synthesis of nonactin SCIE SCOPUS
- Title
- Total synthesis of nonactin
- Date Issued
- 1996-01-08
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Abstract
- Utilizing the efficient preparation of (+)-nonactic acid(2a) and (-)-methyl 8-epi-nonactate (4b) starting from optically active 2-isoxazolines 5a and 5b, respectively, the total synthesis of nonactin has been accomplished. Based on the high dilution Version of the Yamaguchi's method, the final macrolactonization has been completed in high yield.
- Keywords
- BETA-HYDROXY KETONES; SILYL NITRONATE CYCLOADDITIONS; STEREOSELECTIVE SYNTHESIS; ASYMMETRIC-SYNTHESIS; (-)-METHYL 8-EPI-NONACTATE; (+/-)-METHYL NONACTATE; (+/-)-NONACTIC ACID; ACETAL TEMPLATES; REDUCTION; ESTERS
- ISSN
- 0040-4020
- Article Type
- Article
- Citation
- TETRAHEDRON, vol. 52, no. 2, page. 571 - 588, 1996-01-08
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Related Researcher
- 김병현KIM, BYEANG HYEAN
- Div of Advanced Materials Science