DIELECTRIC AND PIEZOELECTRIC PROPERTIES OF THE THERMALLY ANNEALED PB(ZN,MG)(1/3)NB2/3O3-PBTIO3 SYSTEM ACROSS THE RHOMBOHEDRAL TETRAGONAL MORPHOTROPIC PHASE
SCIE
SCOPUS
- Title
- DIELECTRIC AND PIEZOELECTRIC PROPERTIES OF THE THERMALLY ANNEALED PB(ZN,MG)(1/3)NB2/3O3-PBTIO3 SYSTEM ACROSS THE RHOMBOHEDRAL TETRAGONAL MORPHOTROPIC PHASE
- Authors
- JANG, HM; LEE, KM
- Date Issued
- 1995-12
- Publisher
- MATERIALS RESEARCH SOCIETY
- Abstract
- Effects of thermal annealing on the dielectric/piezoelectric properties of Pb(Zn, Mg)(1/3)Nb2/3O3-PbTiO3 ceramics (PZMN-PT with Zn/Mg = 6/4) were examined across the rhombohedral/tetragonal morphotropic phase boundary (MPB). Examination of the lattice parameters and the rhombohedral angle indicated that the MPB is in the vicinity of 24 mol% PbTiO3. Both the relative dielectric permittivity (epsilon(r)) and the piezoelectric constant (d(33))/electromechanical coupling constant (k(p)) were increased by thermal annealing (800-900 degrees C) after sintering at 1150 degrees C for 1 h. The observed improvements in the dielectric and piezoelectric properties were attributed to the elimination of PbO-rich amorphous intergranular layers (about 1 nm thickness) induced by thermal annealing. Both the dielectric analysis using the series mixing model and the microscopic examination by transmission electron microscopy supported this conclusion.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/21686
- DOI
- 10.1557/JMR.1995.3185
- ISSN
- 0884-2914
- Article Type
- Article
- Citation
- JOURNAL OF MATERIALS RESEARCH, vol. 10, no. 12, page. 3185 - 3193, 1995-12
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