DC Field | Value | Language |
---|---|---|
dc.contributor.author | CHO, YG | - |
dc.contributor.author | HUH, S | - |
dc.contributor.author | JUN, MJ | - |
dc.contributor.author | KIM, KM | - |
dc.contributor.author | WHANG, DM | - |
dc.date.accessioned | 2016-03-31T14:37:02Z | - |
dc.date.available | 2016-03-31T14:37:02Z | - |
dc.date.created | 2009-03-23 | - |
dc.date.issued | 1994-06 | - |
dc.identifier.issn | 0277-5387 | - |
dc.identifier.other | 1994-OAK-0000008931 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/21936 | - |
dc.description.abstract | A series of new hydridocarbonyl ruthenium(II) complexes containing chelating diphosphine ligands of the type [RuHCl(CO)(PPh3)(L-L)] [L-L = Ph2PCH2PPh, 2, Ph2PCH2CH2PPh2 3, Ph2PCH2CH2CH2PPh2 4, cis-Ph2PCH=CHPPh2 5 and Fe(eta5-C5H4PPh2)2 6] has been prepared by the reactions of [RuHCI(CO)(PPh3)3] 1 with Ph2PCH2PPh2 [dppm, bis(diphenylphosphino)methane], Ph2PCH2CH2PPh2 [dppe, 1,2-bis(diphenylphosphino)ethane], Ph2PCH2CH2CH2PPh2 [dppp, 1,3-bis(diphenylphosphino)propanel, cis-Ph2PCH=CHPPh2 [dppv, cis-1,2-bis(diphenylphosphino)ethylene] and Fe(eta5-C5H4PPh2)2 [(dppf, 1, l'-bis(diphenylphosphino)ferrocene] in boiling PhMe. The compounds 2-6 are moderately stable in solution. The new compounds were characterized by elemental analysis, IR and H-1 NMR spectroscopy. Compounds 1-6 have been shown to catalyse the homogeneous hydrogenation of the C=C bond of cyclohexene; some relations between structures and catalytic activities are described. The Arrhenius activation energy of cyclohexene for compound 4 is 33.0 kJ mol-1. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.relation.isPartOf | POLYHEDRON | - |
dc.title | THE CATALYTIC ACTIVITY OF NEW RUTHENIUM(II) COMPLEXES CONTAINING CHELATING DIPHOSPHINE LIGAND IN THE HOMOGENEOUS HYDROGENATION OF CYCLOHEXENE | - |
dc.type | Article | - |
dc.contributor.college | 화학과 | - |
dc.identifier.doi | 10.1016/0277-5387(94)80012-X | - |
dc.author.google | CHO, YG | - |
dc.author.google | HUH, S | - |
dc.author.google | JUN, MJ | - |
dc.author.google | KIM, KM | - |
dc.author.google | WHANG, DM | - |
dc.relation.volume | 13 | - |
dc.relation.startpage | 1887 | - |
dc.relation.lastpage | 1894 | - |
dc.contributor.id | 10104366 | - |
dc.relation.journal | POLYHEDRON | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | POLYHEDRON, v.13, no.12, pp.1887 - 1894 | - |
dc.identifier.wosid | A1994NX03300012 | - |
dc.citation.endPage | 1894 | - |
dc.citation.number | 12 | - |
dc.citation.startPage | 1887 | - |
dc.citation.title | POLYHEDRON | - |
dc.citation.volume | 13 | - |
dc.contributor.affiliatedAuthor | KIM, KM | - |
dc.identifier.scopusid | 2-s2.0-0000062331 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 16 | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | OSMIUM COMPLEXES | - |
dc.subject.keywordPlus | ALDEHYDES | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | ALCOHOLS | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordPlus | KETONES | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.relation.journalWebOfScienceCategory | Crystallography | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Crystallography | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
library@postech.ac.kr Tel: 054-279-2548
Copyrights © by 2017 Pohang University of Science ad Technology All right reserved.