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THE SYNTHESIS OF ACETIC-ACID FROM METHYL FORMATE CATALYZED BY NICKEL-COMPLEXES SCIE SCOPUS

Title
THE SYNTHESIS OF ACETIC-ACID FROM METHYL FORMATE CATALYZED BY NICKEL-COMPLEXES
Authors
CHEONG, MKIM, YGLEE, JSLEE, SHSA, YS
Date Issued
1991-09-15
Publisher
ELSEVIER SCIENCE BV
Abstract
A highly efficient catalyst system consisting of a nickel complex, a trialkylamine, and a tetraaklyltin was studied for the isomerization of methyl formate to acetic acid. The effects of temperature, solvent, methyl formate concentration and CO partial pressure on the rate and selectivity of the reaction were investigated. The role of promoter tetraalkyltin as a Lewis acid and synergistic effects between promoters are explained using a proposed mechanism.
URI
https://oasis.postech.ac.kr/handle/2014.oak/22247
DOI
10.1016/0304-5102(91)80086-I
ISSN
0304-5102
Article Type
Article
Citation
JOURNAL OF MOLECULAR CATALYSIS, vol. 68, no. 3, page. 277 - 288, 1991-09-15
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