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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Lee, SJ | - |
| dc.contributor.author | Sung, HR | - |
| dc.contributor.author | Son, JH | - |
| dc.contributor.author | Ramesh, R | - |
| dc.contributor.author | Ahn, KH | - |
| dc.date.accessioned | 2016-04-01T01:55:47Z | - |
| dc.date.available | 2016-04-01T01:55:47Z | - |
| dc.date.created | 2009-08-06 | - |
| dc.date.issued | 2006-05 | - |
| dc.identifier.issn | 1387-7003 | - |
| dc.identifier.other | 2006-OAK-0000005937 | - |
| dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/24023 | - |
| dc.description.abstract | A new class of easily tunable, homochiral tetradentate ligand, (R,R)-[(N-benzyl-N-[2-[N-benzyl-N-(pyridine-2-yl)methyl]amino}-cyclohexyl)amino]acetic acid (2), has been synthesized and characterized by NMR spectroscopy. The synthesis involves highly selective N-alkylation of the 1,2-diamine via an imidazolidine intermediate, giving up to 78% overall yield. The corresponding Co(III) complex of general composition [Co(2a)(NO2)(2)] has been synthesized and the major stereoisomer has been characterized by X-ray crystallography. Molecular calculation at PM3 level indicates that the major isomer is cis-beta-Delta-syn isomer. (C) 2006 Elsevier B.V. All rights reserved. | - |
| dc.description.statementofresponsibility | X | - |
| dc.language | English | - |
| dc.publisher | ELSEVIER SCIENCE BV | - |
| dc.relation.isPartOf | INORGANIC CHEMISTRY COMMUNICATIONS | - |
| dc.subject | N3O-chelate | - |
| dc.subject | tetradentate ligand | - |
| dc.subject | Co(III) complex | - |
| dc.subject | X-ray diffraction | - |
| dc.subject | ALPHA-AMINO-ACIDS | - |
| dc.subject | METAL-COMPLEXES | - |
| dc.subject | COBALT(III) | - |
| dc.title | Synthesis of a homochiral carboxylate-containing tetradentate ligand and its Co(III) complex | - |
| dc.type | Article | - |
| dc.contributor.college | 분자소재융합계의 전자-광 거동연구센터 | - |
| dc.identifier.doi | 10.1016/j.inoche.2006.02.023 | - |
| dc.author.google | Lee, SJ | - |
| dc.author.google | Sung, HR | - |
| dc.author.google | Son, JH | - |
| dc.author.google | Ramesh, R | - |
| dc.author.google | Ahn, KH | - |
| dc.relation.issue | 5 | - |
| dc.relation.startpage | 518 | - |
| dc.relation.lastpage | 521 | - |
| dc.contributor.id | 10087916 | - |
| dc.relation.journal | INORGANIC CHEMISTRY COMMUNICATIONS | - |
| dc.relation.index | SCI급, SCOPUS 등재논문 | - |
| dc.relation.sci | SCI | - |
| dc.collections.name | Journal Papers | - |
| dc.type.rims | ART | - |
| dc.identifier.bibliographicCitation | INORGANIC CHEMISTRY COMMUNICATIONS, v.9, no.5, pp.518 - 521 | - |
| dc.identifier.wosid | 000237634800023 | - |
| dc.date.tcdate | 2019-01-01 | - |
| dc.citation.endPage | 521 | - |
| dc.citation.number | 5 | - |
| dc.citation.startPage | 518 | - |
| dc.citation.title | INORGANIC CHEMISTRY COMMUNICATIONS | - |
| dc.citation.volume | 9 | - |
| dc.contributor.affiliatedAuthor | Ahn, KH | - |
| dc.identifier.scopusid | 2-s2.0-33646140953 | - |
| dc.description.journalClass | 1 | - |
| dc.description.journalClass | 1 | - |
| dc.description.wostc | 2 | - |
| dc.type.docType | Article | - |
| dc.subject.keywordPlus | ALPHA-AMINO-ACIDS | - |
| dc.subject.keywordPlus | METAL | - |
| dc.subject.keywordPlus | COBALT(III) | - |
| dc.subject.keywordAuthor | N3O-chelate | - |
| dc.subject.keywordAuthor | tetradentate ligand | - |
| dc.subject.keywordAuthor | Co(III) complex | - |
| dc.subject.keywordAuthor | X-ray diffraction | - |
| dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
| dc.relation.journalResearchArea | Chemistry | - |
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Related Researcher
- 안교한AHN, KYO HAN
- Dept of Chemistry