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Gold(I)-Catalyzed Synthesis of gamma-Hydroxyketones from 5-Allyloxy-1-ynes SCIE SCOPUS

Title
Gold(I)-Catalyzed Synthesis of gamma-Hydroxyketones from 5-Allyloxy-1-ynes
Authors
Cheong, JYIm, DLee, MLim, WRhee, YH
Date Issued
2011-01-07
Publisher
AMER CHEMICAL SOC
Abstract
The Au(I)-catalyzed reactions of 5-allyloxy-1-ynes gave various gamma-hydroxyketones, via a hydration-terminated domino sequence involving sigmatropic allyl migration as the key event. Moreover, the scope of the sigmatropic allyl transfer was systematically determined.
Keywords
INTRAMOLECULAR CARBOALKOXYLATION; PLATINUM CATALYSIS; GOLD CATALYSIS; CYCLOISOMERIZATION; CYCLIZATION; ALKYNES; REARRANGEMENT; CARBONATES; 1,6-ENYNES; ENYNES
URI
https://oasis.postech.ac.kr/handle/2014.oak/25128
DOI
10.1021/JO102005X
ISSN
0022-3263
Article Type
Article
Citation
JOURNAL OF ORGANIC CHEMISTRY, vol. 76, no. 1, page. 324 - 327, 2011-01-07
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