Gold(I)-Catalyzed Synthesis of gamma-Hydroxyketones from 5-Allyloxy-1-ynes
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- Title
- Gold(I)-Catalyzed Synthesis of gamma-Hydroxyketones from 5-Allyloxy-1-ynes
- Authors
- Cheong, JY; Im, D; Lee, M; Lim, W; Rhee, YH
- Date Issued
- 2011-01-07
- Publisher
- AMER CHEMICAL SOC
- Abstract
- The Au(I)-catalyzed reactions of 5-allyloxy-1-ynes gave various gamma-hydroxyketones, via a hydration-terminated domino sequence involving sigmatropic allyl migration as the key event. Moreover, the scope of the sigmatropic allyl transfer was systematically determined.
- Keywords
- INTRAMOLECULAR CARBOALKOXYLATION; PLATINUM CATALYSIS; GOLD CATALYSIS; CYCLOISOMERIZATION; CYCLIZATION; ALKYNES; REARRANGEMENT; CARBONATES; 1,6-ENYNES; ENYNES
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/25128
- DOI
- 10.1021/JO102005X
- ISSN
- 0022-3263
- Article Type
- Article
- Citation
- JOURNAL OF ORGANIC CHEMISTRY, vol. 76, no. 1, page. 324 - 327, 2011-01-07
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- There are no files associated with this item.
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