DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jung, GS | - |
dc.contributor.author | Park, DH | - |
dc.contributor.author | Lee, DH | - |
dc.contributor.author | Lee, HC | - |
dc.contributor.author | Hong, SB | - |
dc.contributor.author | Woo, HC | - |
dc.date.accessioned | 2016-04-01T02:29:56Z | - |
dc.date.available | 2016-04-01T02:29:56Z | - |
dc.date.created | 2010-12-17 | - |
dc.date.issued | 2010-10-11 | - |
dc.identifier.issn | 0926-3373 | - |
dc.identifier.other | 2010-OAK-0000022495 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/25244 | - |
dc.description.abstract | The adsorptive removal of tert-butylmercaptan (TBM) and tetrahydrothiophene (THT) in methane gas using microporous molecular sieve ETS-10 was investigated at an ambient temperature and atmospheric pressure. Na,K-ETS-10 and Cu-exchanged Na,K-ETS-10 (Cu-ETS-10) were characterized by X-ray diffractometer (XRD) for the crystalline phase, X-ray fluorescence (XRF) analyzer for the chemical composition, and nitrogen adsorption-isotherm measurement for the BET surface area and porosity, respectively. Posterior to its treatment at 723 K in He atmosphere for 2h, the Cu(II) in Cu-ETS-10 could be partially autoreduced to Cu(I), which was confirmed by X-ray photoelectron spectroscopy (XPS). The preferential adsorption of THT over TBM on Na,K-ETS-10 and the concurrent adsorption of TBM and THT on Cu-ETS-10 were achieved, which could be explained by the uptake curve in the binary component adsorption, the temperature-programmed desorption, and the apparent activation energy for desorption. The breakthrough sulfur adsorption capacity for both TBM and THT was attained to 2.50 mmol S/g on Cu-ETS-10-0.1(4). This markedly high breakthrough sulfur adsorption capacity on Cu-ETS-10 is unprecedented in removing organic sulfur compounds from fuel gas by adsorption on zeolites. (C) 2010 Elsevier B.V. All rights reserved. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | ELSEVIER SCIENCE BV | - |
dc.relation.isPartOf | APPLIED CATALYSIS B-ENVIRONMENTAL | - |
dc.subject | Adsorption | - |
dc.subject | Desulfurization | - |
dc.subject | Cu-exchanged ETS-10 | - |
dc.subject | Zeolite | - |
dc.subject | FUEL-CELL APPLICATIONS | - |
dc.subject | SELECTIVE ADSORPTION | - |
dc.subject | AMBIENT CONDITIONS | - |
dc.subject | PI-COMPLEXATION | - |
dc.subject | JET FUEL | - |
dc.subject | DESULFURIZATION | - |
dc.subject | ZEOLITES | - |
dc.subject | DIESEL | - |
dc.subject | ADSORBENTS | - |
dc.subject | THIOPHENE | - |
dc.title | Adsorptive removal of tert-butylmercaptan and tetrahydrothiophene using microporous molecular sieve ETS-10 | - |
dc.type | Article | - |
dc.contributor.college | 환경공학부 | - |
dc.identifier.doi | 10.1016/J.APCATB.2010.08.002 | - |
dc.author.google | Jung, GS | - |
dc.author.google | Park, DH | - |
dc.author.google | Lee, DH | - |
dc.author.google | Lee, HC | - |
dc.author.google | Hong, SB | - |
dc.author.google | Woo, HC | - |
dc.relation.volume | 100 | - |
dc.relation.issue | 1 | - |
dc.relation.startpage | 264 | - |
dc.relation.lastpage | 270 | - |
dc.contributor.id | 10077624 | - |
dc.relation.journal | APPLIED CATALYSIS B-ENVIRONMENTAL | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | APPLIED CATALYSIS B-ENVIRONMENTAL, v.100, no.1, pp.264 - 270 | - |
dc.identifier.wosid | 000283963000033 | - |
dc.date.tcdate | 2019-02-01 | - |
dc.citation.endPage | 270 | - |
dc.citation.number | 1 | - |
dc.citation.startPage | 264 | - |
dc.citation.title | APPLIED CATALYSIS B-ENVIRONMENTAL | - |
dc.citation.volume | 100 | - |
dc.contributor.affiliatedAuthor | Hong, SB | - |
dc.identifier.scopusid | 2-s2.0-77957239720 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 10 | - |
dc.description.scptc | 11 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article | - |
dc.subject.keywordPlus | FUEL-CELL APPLICATIONS | - |
dc.subject.keywordPlus | SELECTIVE ADSORPTION | - |
dc.subject.keywordPlus | AMBIENT CONDITIONS | - |
dc.subject.keywordPlus | PI-COMPLEXATION | - |
dc.subject.keywordPlus | JET FUEL | - |
dc.subject.keywordPlus | DESULFURIZATION | - |
dc.subject.keywordPlus | ZEOLITES | - |
dc.subject.keywordPlus | DIESEL | - |
dc.subject.keywordPlus | ADSORBENTS | - |
dc.subject.keywordPlus | THIOPHENE | - |
dc.subject.keywordAuthor | Adsorption | - |
dc.subject.keywordAuthor | Desulfurization | - |
dc.subject.keywordAuthor | Cu-exchanged ETS-10 | - |
dc.subject.keywordAuthor | Zeolite | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Engineering, Environmental | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Engineering | - |
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