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Asymmetric [2+2] olefin cross photoaddition in a self-assembled host with remote chiral auxiliaries SCIE SCOPUS
- Title
- Asymmetric [2+2] olefin cross photoaddition in a self-assembled host with remote chiral auxiliaries
- Authors
- Nishioka, Y; Yamaguchi, T; Kawano, M; Fujita, M
- Date Issued
- 2008-07-02
- Publisher
- AMER CHEMICAL SOC
- Abstract
- Remote chaiarlity at the periphery of a self-assembled cage brings about the slight twist of aromatic rings, which is yet sufficient to induce considerable asymmetric induction (up to 50% ee) in the hitherto unknow [2+2] cross photoadditions of fluoranthenes.
- Keywords
- DIELS-ALDER REACTIONS; ENANTIODIFFERENTIATING 4+4 PHOTOCYCLODIMERIZATION; COORDINATION CAGE; SUPRAMOLECULAR CATALYSIS; GAMMA-CYCLODEXTRIN; MOLECULAR CAPSULE; CONFINED CAVITY; BASIC SOLUTION; 2-ANTHRACENECARBOXYLATE; PHOTOISOMERIZATION
- ISSN
- 0002-7863
- Article Type
- Article
- Citation
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 130, no. 26, page. 8160 - +, 2008-07-02
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Related Researcher
- KawanoMasakiKAWANO, MASAKI
- Div of Advanced Materials Science