The first tin(IV) porphyrin complex with chiral amino acid ligands: synthesis, characterization and X-ray crystal structure of trans-bis(L-prolinato)[5,10,15,20-tetrakis(4-pyridyl)porphyrinato]tin(IV)
SCIE
SCOPUS
- Title
- The first tin(IV) porphyrin complex with chiral amino acid ligands: synthesis, characterization and X-ray crystal structure of trans-bis(L-prolinato)[5,10,15,20-tetrakis(4-pyridyl)porphyrinato]tin(IV)
- Authors
- Kim, SH; Kim, H; Kim, K; Kim, HJ
- Date Issued
- 2009-07
- Publisher
- WORLD SCI PUBL CO INC
- Abstract
- The tin(IV) porphyrin complex with chiral amino acid ligands trans-bis(L-prolinato)[5,10,15,20-tetrakis(4-pyridyl) porphyrinato] tin(IV) (1) was synthesized and fully characterized. The X-ray crystal structural analysis of 1 reveals that the Sn(IV) center is octahedrally coordinated by the porphyrin occupying the square base and axial coordination of two L-prolinate ligands in trans-position with respect to each other. The pyrrolidine rings of the L-prolinate ligands in 1 exhibit a C-s-C-beta-exo envelope conformation with C-s symmetry. The non-classical hydrogen bonding interactions mainly contribute to assemble 1 into a one-dimensional packed structure.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/26455
- DOI
- 10.1142/S108842460900098X
- ISSN
- 1088-4246
- Article Type
- Article
- Citation
- JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, vol. 13, no. 7, page. 805 - 810, 2009-07
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