DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, C | - |
dc.contributor.author | Bae, HJ | - |
dc.contributor.author | Lee, JH | - |
dc.contributor.author | Jeong, W | - |
dc.contributor.author | Kim, H | - |
dc.contributor.author | Sampath, V | - |
dc.contributor.author | Rhee, YH | - |
dc.date.accessioned | 2016-04-01T08:21:18Z | - |
dc.date.available | 2016-04-01T08:21:18Z | - |
dc.date.created | 2009-11-25 | - |
dc.date.issued | 2009-10-21 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.other | 2009-OAK-0000019374 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/27785 | - |
dc.description.abstract | A new gold (I)-catalyzed cycloisomerization to access highly substituted piperidines has been developed. By combining a conceptually new way of generating iminium ions using cationic gold(I) complexes and an efficient cyclization reaction that can minimize a potentially competing aza-Cope rearrangement, the proposed reaction successfully circumvents a long-standing problem in the classical aza-Prins reaction. Synthetic utility of the catalytic reaction was demonstrated by a synthesis of optically active 2-alkyl-pipendin-4-one. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.relation.isPartOf | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.subject | GOLD CATALYSIS | - |
dc.subject | INTRAMOLECULAR CARBOALKOXYLATION | - |
dc.subject | AU CATALYSIS | - |
dc.subject | PLATINUM | - |
dc.subject | REARRANGEMENTS | - |
dc.subject | ALKALOIDS | - |
dc.subject | EPOXIDES | - |
dc.subject | ENYNES | - |
dc.subject | ACIDS | - |
dc.title | Formal Alkyne Aza-Prins Cyclization: Gold(I)-Catalyzed Cycloisomerization of Mixed N,O-Acetals Generated from Homopropargylic Amines to Highly Substituted Piperidines | - |
dc.type | Article | - |
dc.contributor.college | 화학과 | - |
dc.identifier.doi | 10.1021/JA906744R | - |
dc.author.google | Kim, C | - |
dc.author.google | Bae, HJ | - |
dc.author.google | Lee, JH | - |
dc.author.google | Jeong, W | - |
dc.author.google | Kim, H | - |
dc.author.google | Sampath, V | - |
dc.author.google | Rhee, YH | - |
dc.relation.volume | 131 | - |
dc.relation.issue | 41 | - |
dc.relation.startpage | 14660 | - |
dc.relation.lastpage | 14661 | - |
dc.contributor.id | 10153778 | - |
dc.relation.journal | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.131, no.41, pp.14660 - 14661 | - |
dc.identifier.wosid | 000271271800031 | - |
dc.date.tcdate | 2019-02-01 | - |
dc.citation.endPage | 14661 | - |
dc.citation.number | 41 | - |
dc.citation.startPage | 14660 | - |
dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.volume | 131 | - |
dc.contributor.affiliatedAuthor | Rhee, YH | - |
dc.identifier.scopusid | 2-s2.0-70350054832 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 64 | - |
dc.description.scptc | 5 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article | - |
dc.subject.keywordPlus | GOLD CATALYSIS | - |
dc.subject.keywordPlus | INTRAMOLECULAR CARBOALKOXYLATION | - |
dc.subject.keywordPlus | AU CATALYSIS | - |
dc.subject.keywordPlus | PLATINUM | - |
dc.subject.keywordPlus | REARRANGEMENTS | - |
dc.subject.keywordPlus | ALKALOIDS | - |
dc.subject.keywordPlus | EPOXIDES | - |
dc.subject.keywordPlus | ENYNES | - |
dc.subject.keywordPlus | ACIDS | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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