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Oxidative Degradation of Organic Compounds Using Zero-Valent Iron in the Presence of Natural Organic Matter Serving as an Electron Shuttle SCIE SCOPUS

Title
Oxidative Degradation of Organic Compounds Using Zero-Valent Iron in the Presence of Natural Organic Matter Serving as an Electron Shuttle
Authors
Kang, SHChoi, W
Date Issued
2009-02-01
Publisher
AMER CHEMICAL SOC
Abstract
This study aims to understand the oxidative degradation of organic compounds utilizing zerovalent iron (ZVI) which is further promoted by the presence of natural organic matters (NOMs) (as humic acid (HA) or fulvic acid (FA)) working as electron shuttle mediators. The main target substrate used was 4-chlorophenol. Both HA and FA can mediate the electron transfer from the ZVI surface to O-2, while enhancing the production of Fe2+ and H2O2 that subsequently initiates the OH radical-mediated oxidation of organic compounds through Fenton reaction. The electron transfer-mediating role of NOMs was supported by the observation that higher concentrations of H2O2 and ferrous ion were generated in the presence of NOM. The NOW induced enhancement in oxidation was observed with NOM concentrations ranging 0.1-10 ppm. Since the reactive sites responsible for the electron transfer action are likely to be the quinone moieties of NOMs, benzoquinone that was tested as a proxy of NOM also enhanced the oxidative degradation of 4-chlorophenol in the ZVI suspension. The NOM-mediated oxidation reaction on ZVI was completely inhibited in the presence of methanol, an OH radical scavenger, and in the absence of dissolved oxygen.
Keywords
HUMIC-ACID; HYDROGEN-PEROXIDE; ZEROVALENT IRON; FULVIC-ACID; REDUCTIVE DEHALOGENATION; FE(II) OXIDATION; NEUTRAL PH; FENTON; DECHLORINATION; GROUNDWATER
URI
https://oasis.postech.ac.kr/handle/2014.oak/29156
DOI
10.1021/ES801705F
ISSN
0013-936X
Article Type
Article
Citation
ENVIRONMENTAL SCIENCE & TECHNOLOGY, vol. 43, no. 3, page. 878 - 883, 2009-02-01
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최원용CHOI, WONYONG
Div of Environmental Science & Enginrg
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