DC Field | Value | Language |
---|---|---|
dc.contributor.author | Ko, KB | - |
dc.contributor.author | Byun, Y | - |
dc.contributor.author | Cho, M | - |
dc.contributor.author | Namkung, W | - |
dc.contributor.author | Hamilton, IP | - |
dc.contributor.author | Shin, DN | - |
dc.contributor.author | Koh, DJ | - |
dc.contributor.author | Kim, KT | - |
dc.date.accessioned | 2017-07-18T17:01:11Z | - |
dc.date.available | 2017-07-18T17:01:11Z | - |
dc.date.created | 2009-08-05 | - |
dc.date.issued | 2008-09 | - |
dc.identifier.issn | 1024-1221 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/31122 | - |
dc.description.abstract | This study examines the effect of flue gas components on the oxidation of gaseous elemental mercury (Hg-0) to HgO and HgCl2 via pulsed corona discharge (PCD), where the reaction temperature was set to 90 degrees C and the gas stream consisting of 3% H2O and 10% O-2 in N-2 was mixed with 45 mu g m(-3) Hg-0, 108 ppm NOx, 80 ppm HCl, 200 ppm SO2 and 470 ppm NH3. It has been observed that O-2 and HCl components in the gas stream act as oxidizing precursors through the generation of oxidizing species (O, O-3, Cl and Cl-2) in the PCD process. The presence of NO directly hampers Hg-0 oxidation to HgO due to preferential reaction of NO with O and O-3. In contrast, the presence of SO2 indirectly influences the oxidation of Hg-0 to HgCl2 through the fast reaction of SO2 with OH radical, resulting in consuming OH radicals which are partially responsible for the formation of chlorine species, i. e. Cl and Cl-2. It has been also found that NH3 component significantly hinders the oxidation of Hg-0 to HgCl2 through the fast acid-base reaction with HCl. | - |
dc.language | English | - |
dc.publisher | TAYLOR & FRANCIS LTD | - |
dc.relation.isPartOf | MAIN GROUP CHEMISTRY | - |
dc.subject | pulsed corona discharge | - |
dc.subject | elemental mercury | - |
dc.subject | oxidized mercury | - |
dc.subject | HgO | - |
dc.subject | HgCl(2) | - |
dc.subject | DIELECTRIC-BARRIER DISCHARGE | - |
dc.subject | SIMULTANEOUS REMOVAL | - |
dc.subject | NONTHERMAL PLASMA | - |
dc.subject | FLUE-GAS | - |
dc.subject | SO2 | - |
dc.subject | REACTOR | - |
dc.subject | ATMOSPHERE | - |
dc.subject | SPECIATION | - |
dc.subject | INJECTION | - |
dc.subject | EMISSIONS | - |
dc.title | Influence of gas components on the oxidation of elemental mercury by positive pulsed corona discharge | - |
dc.type | Article | - |
dc.identifier.doi | 10.1080/102412208026 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | MAIN GROUP CHEMISTRY, v.7, no.3, pp.191 - 204 | - |
dc.identifier.wosid | 000262005800004 | - |
dc.date.tcdate | 2019-03-01 | - |
dc.citation.endPage | 204 | - |
dc.citation.number | 3 | - |
dc.citation.startPage | 191 | - |
dc.citation.title | MAIN GROUP CHEMISTRY | - |
dc.citation.volume | 7 | - |
dc.contributor.affiliatedAuthor | Cho, M | - |
dc.contributor.affiliatedAuthor | Namkung, W | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 11 | - |
dc.type.docType | Article; Proceedings Paper | - |
dc.subject.keywordPlus | SIMULTANEOUS REMOVAL | - |
dc.subject.keywordPlus | SO2 | - |
dc.subject.keywordPlus | SPECIATION | - |
dc.subject.keywordPlus | EMISSIONS | - |
dc.subject.keywordPlus | INJECTION | - |
dc.subject.keywordPlus | REACTOR | - |
dc.subject.keywordPlus | H2O | - |
dc.subject.keywordPlus | HCL | - |
dc.subject.keywordPlus | NOX | - |
dc.subject.keywordPlus | HG | - |
dc.subject.keywordAuthor | pulsed corona discharge | - |
dc.subject.keywordAuthor | elemental mercury | - |
dc.subject.keywordAuthor | oxidized mercury | - |
dc.subject.keywordAuthor | HgO | - |
dc.subject.keywordAuthor | HgCl2 | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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