DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Y | - |
dc.contributor.author | Yang, T | - |
dc.contributor.author | Yun, G | - |
dc.contributor.author | Ghasemian, MB | - |
dc.contributor.author | Koo, J | - |
dc.contributor.author | Lee, E | - |
dc.contributor.author | Cho, SJ | - |
dc.contributor.author | Kim, K | - |
dc.date.accessioned | 2017-07-19T12:12:30Z | - |
dc.date.available | 2017-07-19T12:12:30Z | - |
dc.date.created | 2016-01-12 | - |
dc.date.issued | 2015-11-02 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/35438 | - |
dc.description.abstract | A new approach to the synthesis of hierarchical micro- and mesoporous MOFs from microporous MOFs involves a simple hydrolytic post-synthetic procedure. As a proof of concept, a new microporous MOF, POST-66(Y), was synthesized and its transformation into a hierarchical micro- and mesoporous MOF by water treatment was studied. This method produced mesopores in the range of 3 to 20nm in the MOF while maintaining the original microporous structure, at least in part. The degree of micro- and mesoporosity can be controlled by adjusting the time and temperature of hydrolysis. The resulting hierarchical porous MOF, POST-66(Y)-wt, can be utilized to encapsulate nanometer-sized guests such as proteins, and the enhanced stability and recyclability of an encapsulated enzyme is demonstrated. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.relation.isPartOf | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.title | Hydrolytic Transformation of Microporous Metal-Organic Frameworks to Hierarchical Micro- and Mesoporous MOFs | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/ANIE.201506391 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.54, no.45, pp.13273 - 13278 | - |
dc.identifier.wosid | 000363691500019 | - |
dc.date.tcdate | 2019-03-01 | - |
dc.citation.endPage | 13278 | - |
dc.citation.number | 45 | - |
dc.citation.startPage | 13273 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 54 | - |
dc.contributor.affiliatedAuthor | Lee, E | - |
dc.contributor.affiliatedAuthor | Kim, K | - |
dc.identifier.scopusid | 2-s2.0-84946485922 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 41 | - |
dc.description.scptc | 20 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article | - |
dc.subject.keywordPlus | SYNTHETIC ROUTE | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
dc.subject.keywordPlus | EXCHANGE | - |
dc.subject.keywordPlus | POROSITY | - |
dc.subject.keywordPlus | METATHESIS | - |
dc.subject.keywordAuthor | hierarchical porosity | - |
dc.subject.keywordAuthor | mesoporous materials | - |
dc.subject.keywordAuthor | metal-organic frameworks | - |
dc.subject.keywordAuthor | post-synthetic transformation | - |
dc.subject.keywordAuthor | protein immobilization | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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